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Sodium bis(2-methoxyethoxy)aluminum hydride, 70% w/w in toluene., Thermo Scientific Chemicals

$65.41 - $378.70

Chemical Identifiers

CAS 22722-98-1
Molecular Formula C6H16AlNaO4
MDL Number MFCD00011631
Synonym Sodium dihydrobis(2-methoxyethoxy)aluminate
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Products 3
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AAA1329218
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Thermo Scientific Chemicals
A1329218
50 g
Each for $65.41
 
AAA1329230
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Thermo Scientific Chemicals
A1329230
250 g
Each for $116.34
 
AAA132920B
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Thermo Scientific Chemicals
A132920B
1000 g
Each for $378.70
 
Description

Description

Sodium bis(2-methoxyethoxy)aluminum hydride acts as a reducing agent in organic synthesis. It is used to prepare azoxyarenes, azoarenes and hydroazoarenes from nitroarenes. It plays an important role for the conversion of aldehydes, ketones, carboxylic acids, esters, acyl halides and anhydrides to primary alcohols. It is also employed in hydroaluminate alkenes and alkynes. It is utilized in the reduction of lactones and epoxides into diols. Further, it serves as a methylation reagent for aryl-activated compounds. In addition to this, it is involved in the reduction of amides, nitriles and amines to the corresponding amines.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Sodium bis(2-methoxyethoxy)aluminum hydride acts as a reducing agent in organic synthesis. It is used to prepare azoxyarenes, azoarenes and hydroazoarenes from nitroarenes. It plays an important role for the conversion of aldehydes, ketones, carboxylic acids, esters, acyl halides and anhydrides to primary alcohols. It is also employed in hydroaluminate alkenes and alkynes. It is utilized in the reduction of lactones and epoxides into diols. Further, it serves as a methylation reagent for aryl-activated compounds. In addition to this, it is involved in the reduction of amides, nitriles and amines to the corresponding amines.

Solubility
Miscible with aromatic hydrocarbons, ether, tetrahydrofuran, dimethyl ether and dimethylformamide. Immiscible with aliphatic hydrocarbons.

Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with water, oxidizing agents and combustible material.
Specifications

Chemical Identifiers

22722-98-1
C6H16AlNaO4
MFCD00011631
Sodium dihydrobis(2-methoxyethoxy)aluminate

Specifications

22722-98-1
4°C (39°F)
NaAlH2(OCH2CH2OCH3)2
50 g
Moisture sensitive
Sodium dihydrobis(2-methoxyethoxy)aluminate
202.16
1.02
C6H16AlNaO4
MFCD00011631
UN3399
14,8565
Miscible with aromatic hydrocarbons,ether,tetrahydrofuran,dimethyl ether and dimethylformamide. Immiscible with aliphatic hydrocarbons.
Sodium bis(2-methoxyethoxy)aluminum hydride
Safety and Handling

Safety and Handling

GHS H Statement
H225-H260-H304-H361-H373-H314-H332-H336
Highly flammable liquid and vapour.
In contact with water releases flammable gases which may ignite spontaneously.
May be fatal if swallowed and enters airways.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Causes severe skin burns and eye damage.
Harmful if inhaled.
May cause drowsiness or dizziness.

P201-P202-P210-P233-P240-P241-P242-P243-P261-P262-P264b-P271-P280-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P310-P312-P330-P331-P363-P372-P374-P380-P501c

H225-H304-H314-H318-H361-H373-X

DOTInformation : Transport Hazard Class: 4.3; Packing Group: I; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE

EINECSNumber : 245-178-2

TSCA : Yes

Recommended Storage : Ambient temperatures

SDS
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RUO – Research Use Only