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Sodium bis(2-methoxyethoxy)aluminum hydride, 70% w/w in toluene.

Catalog No. p-7021096
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Quantity:
1000 g
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50 g
Catalog No. Quantity
AAA1329218 50 g
AAA1329230 250 g
AAA132920B 1000 g
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Catalog No. AAA1329218

Supplier: Thermo Scientific Chemicals A1329218

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Description

CAS: 22722-98-1 | C6H16AlNaO4

Sodium bis(2-methoxyethoxy)aluminum hydride acts as a reducing agent in organic synthesis. It is used to prepare azoxyarenes, azoarenes and hydroazoarenes from nitroarenes. It plays an important role for the conversion of aldehydes, ketones, carboxylic acids, esters, acyl halides and anhydrides to primary alcohols. It is also employed in hydroaluminate alkenes and alkynes. It is utilized in the reduction of lactones and epoxides into diols. Further, it serves as a methylation reagent for aryl-activated compounds. In addition to this, it is involved in the reduction of amides, nitriles and amines to the corresponding amines.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Sodium bis(2-methoxyethoxy)aluminum hydride acts as a reducing agent in organic synthesis. It is used to prepare azoxyarenes, azoarenes and hydroazoarenes from nitroarenes. It plays an important role for the conversion of aldehydes, ketones, carboxylic acids, esters, acyl halides and anhydrides to primary alcohols. It is also employed in hydroaluminate alkenes and alkynes. It is utilized in the reduction of lactones and epoxides into diols. Further, it serves as a methylation reagent for aryl-activated compounds. In addition to this, it is involved in the reduction of amides, nitriles and amines to the corresponding amines.

Solubility
Miscible with aromatic hydrocarbons, ether, tetrahydrofuran, dimethyl ether and dimethylformamide. Immiscible with aliphatic hydrocarbons.

Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with water, oxidizing agents and combustible material.

Chemical Identifiers

CAS 22722-98-1
Molecular Formula C6H16AlNaO4
MDL Number MFCD00011631
Synonym Sodium dihydrobis(2-methoxyethoxy)aluminate

Specifications

Density 1.02
Flash Point 4°C (39°F)
Linear Formula NaAlH2(OCH2CH2OCH3)2
Quantity 50 g
UN Number UN3399
Sensitivity Moisture sensitive
Merck Index 14,8565
Solubility Information Miscible with aromatic hydrocarbons,ether,tetrahydrofuran,dimethyl ether and dimethylformamide. Immiscible with aliphatic hydrocarbons.
Formula Weight 202.16
Chemical Name or Material Sodium bis(2-methoxyethoxy)aluminum hydride

Safety and Handling

Hazard Category H225-H304-H314-H318-H361-H373-X
Hazard Statement GHS H Statement
H225-H260-H304-H361-H373-H314-H332-H336
Highly flammable liquid and vapour.
In contact with water releases flammable gases which may ignite spontaneously.
May be fatal if swallowed and enters airways.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Causes severe skin burns and eye damage.
Harmful if inhaled.
May cause drowsiness or dizziness.
Precautionary Statement P201-P202-P210-P233-P240-P241-P242-P243-P261-P262-P264b-P271-P280-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P310-P312-P330-P331-P363-P372-P374-P380-P501c
DOTInformation Transport Hazard Class: 4.3; Packing Group: I; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE
EINECSNumber 245-178-2
TSCA Yes
Recommended Storage Ambient temperatures

RUO – Research Use Only