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  7. (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 98+%

(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 98+%

Catalog No. AAL1413703
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Catalog No. AAL1413703 Supplier Thermo Scientific Chemicals Supplier No. L1413703
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Description

CAS: 35193-64-7 | C20H13O4P | 348.294 g/mol

Used as a chiral Bronsted acid catalyst in the enantoselective Mannich reaction.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Used as a chiral Bronsted acid catalyst in the enantoselective Mannich reaction.

Solubility
Soluble in DMSO and methanol (hot).

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agents.

Chemical Identifiers

CAS 35193-64-7
Molecular Formula C20H13O4P
Molecular Weight (g/mol) 348.294
MDL Number MFCD00010045
InChI Key JEHUZVBIUCAMRZ-UHFFFAOYSA-N
Synonym 1,1'-binaphthyl-2,2'-diyl hydrogenphosphate, s-+-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate, r---1,1'-binaphthyl-2,2'-diyl hydrogenphosphate, 1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, r---bnp acid, 11bs-4-hydroxydinaphtho 2,1-d:1',2'-f 1,3,2 dioxaphosphepine 4-oxide, r---1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, r-4-hydroxydinaphtho 2,1-d:1',2'-f 1,3,2 dioxaphosphepine 4-oxide, s-+-bnp acid, 4-hydroxydinaphtho 2,1-d:1',2'-f 1,3,2 dioxaphosphepine 4-oxide
PubChem CID 99589
SMILES C1=CC=C2C(=C1)C=CC3=C2C4=C(C=CC5=CC=CC=C54)OP(=O)(O3)O

Specifications

Melting Point >300°C
Quantity 1 g
Beilstein 4787775
Solubility Information Soluble in DMSO and methanol (hot).
Optical Rotation +605° (c=1 in Methanol)
Formula Weight 348.3
Percent Purity ≥98%
Chemical Name or Material (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate

Safety and Handling

Hazard Category H315-H319-H335
Hazard Statement GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
TSCA No
Recommended Storage Ambient temperatures

RUO – Research Use Only