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Ruthenium(III) 2,4-pentanedionate, Ru 24% min

For Hydrogenation | CAS: 14284-93-6 | C15H21O6Ru | 398.40 g/mol

Supplier:  Thermo Scientific Chemicals 01056803

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Catalog No. AA1056803


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Description

Description

Precursor for the preparation of other compounds of ruthenium. Ruthenium(III) 2,4-pentanedionate is employed as a recyclable catalyst for certain organic transformations like the acetylation of phenols, alcohols, and amines under neat conditions. It is also used as a homogeneous catalyst, for example, in the hydrolysis of sodium borohydride and regiospecific tritiation of aromatic carboxylic acids. It is also used as a catalyst for enantioselective hydrogenation of acids such as aryl acrylic acid and aryl propenic acid.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Specifications

Ruthenium(III) 2, 4-pentanedionate
Ru 24% min.
14284-93-6
1 g
MFCD00000030
Soluble in most organic solvents such as acetone,chlorinated hydrocarbons,alcohols,cyclohexane and benzene. Insoluble in water.
[Ru+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O
398.40
398.4
260°C (decomposition)
White
Crystalline
C15H21O6Ru
ruthenium acetylacetonate, ruthenium iii acetylacetonate, acetylacetone ruthenium iii salt, tris 2,4-pentanedionato ruthenium iii, tris pentane-2,4-dionato-o,o' ruthenium, ruthenium, tris 2,4-pentanedionato-o,o'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-kappao,kappao'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-8ci, z-4-oxopent-2-en-2-olate; ruthenium 3+
RTZYCRSRNSTRGC-LNTINUHCSA-K
(Z)-4-oxopent-2-en-2-olate;ruthenium(3+)
5488829
Red crystals

Chemical Identifiers

14284-93-6
398.40
RTZYCRSRNSTRGC-LNTINUHCSA-K
5488829
C15H21O6Ru
MFCD00000030
ruthenium acetylacetonate, ruthenium iii acetylacetonate, acetylacetone ruthenium iii salt, tris 2,4-pentanedionato ruthenium iii, tris pentane-2,4-dionato-o,o' ruthenium, ruthenium, tris 2,4-pentanedionato-o,o'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-kappao,kappao'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-8ci, z-4-oxopent-2-en-2-olate; ruthenium 3+
[Ru+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O
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Safety and Handling

Safety and Handling

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

EINECSNumber : 238-193-0

TSCA : Yes

Recommended Storage : Ambient temperatures

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