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Pyridinium chlorochromate, 98%
CAS: 26299-14-9 | C5H6ClCrNO3
$55.08 - $460.74
Chemical Identifiers
| CAS | 26299-14-9 |
|---|---|
| Molecular Formula | C5H6ClCrNO3 |
| MDL Number | MFCD00013106 |
| Synonym | PCC |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
|---|---|---|---|---|---|---|---|---|---|
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAA1175214
|
Thermo Scientific Chemicals
A1175214 |
25 g |
Each for $55.08
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AAA1175222
|
Thermo Scientific Chemicals
A1175222 |
100 g |
Each for $135.58
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AAA1175236
|
Thermo Scientific Chemicals
A1175236 |
500 g |
Each for $460.74
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Description
Pyridinium chlorochromate is used as an oxidizing agent to convert primary and secondary alcohols to aldehydes and ketones respectively. It is involved in the preparation of cyclohexanone, (-)-pulegone and lactones. It plays an important role in the selective mono-oxidation of xylenes to tolualdehydes and arylhydroxyamines to nitroso compounds. Furthermore, it is utilized as an oxidant for amino acids, L-cystine, aniline, cycloalkanols, vicinal and non-vicinal diols as well as in the Babler oxidation reaction.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsPyridinium chlorochromate is used as an oxidizing agent to convert primary and secondary alcohols to aldehydes and ketones respectively. It is involved in the preparation of cyclohexanone, (-)-pulegone and lactones. It plays an important role in the selective mono-oxidation of xylenes to tolualdehydes and arylhydroxyamines to nitroso compounds. Furthermore, it is utilized as an oxidant for amino acids, L-cystine, aniline, cycloalkanols, vicinal and non-vicinal diols as well as in the Babler oxidation reaction.
Solubility
Soluble in acetone, benzene, dichloromethane, acetonitrile and tetrahydrofuran.
Notes
Incompatible with alcohols, acetone and methanol.
Chemical Identifiers
| 26299-14-9 | |
| C5H6ClCrNO3 | |
| MFCD00013106 | |
| PCC |
Specifications
| 26299-14-9 | |
| C5H6ClCrNO3 | |
| 25 g | |
| Moisture sensitive | |
| PCC | |
| 215.56 | |
| Pyridinium chlorochromate |
| ∼206°C (decomposition) | |
| MFCD00013106 | |
| UN1479 | |
| 14,7974 | |
| Soluble in acetone,benzene,dichloromethane,acetonitrile and tetrahydrofuran. | |
| 98% |
Safety and Handling
GHS H Statement
H350-H272-H317
May cause cancer.
May intensify fire
oxidizer.
May cause an allergic skin reaction.
P201-P202-P210-P220-P221-P261-P272-P280g-P281-P302+P352-P308+P313-P333+P313-P363-P370+P378q-P501c
H272-H317-H350i
DOTInformation : Transport Hazard Class: 5.1; Packing Group: II; Proper Shipping Name: OXIDIZING SOLID, N.O.S.
EINECSNumber : 247-595-5
TSCA : Yes
Recommended Storage : Ambient temperatures
RUO – Research Use Only