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Pyridinium chlorochromate, 98%

CAS: 26299-14-9 | C5H6ClCrNO3

Supplier:  Thermo Scientific Chemicals A1175214

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Catalog No. AAA1175214


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Description

Description

Pyridinium chlorochromate is used as an oxidizing agent to convert primary and secondary alcohols to aldehydes and ketones respectively. It is involved in the preparation of cyclohexanone, (-)-pulegone and lactones. It plays an important role in the selective mono-oxidation of xylenes to tolualdehydes and arylhydroxyamines to nitroso compounds. Furthermore, it is utilized as an oxidant for amino acids, L-cystine, aniline, cycloalkanols, vicinal and non-vicinal diols as well as in the Babler oxidation reaction.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Pyridinium chlorochromate is used as an oxidizing agent to convert primary and secondary alcohols to aldehydes and ketones respectively. It is involved in the preparation of cyclohexanone, (-)-pulegone and lactones. It plays an important role in the selective mono-oxidation of xylenes to tolualdehydes and arylhydroxyamines to nitroso compounds. Furthermore, it is utilized as an oxidant for amino acids, L-cystine, aniline, cycloalkanols, vicinal and non-vicinal diols as well as in the Babler oxidation reaction.

Solubility
Soluble in acetone, benzene, dichloromethane, acetonitrile and tetrahydrofuran.

Notes
Incompatible with alcohols, acetone and methanol.
Specifications

Specifications

Pyridinium chlorochromate
∼206°C (decomposition)
MFCD00013106
UN1479
14,7974
Soluble in acetone,benzene,dichloromethane,acetonitrile and tetrahydrofuran.
98%
26299-14-9
C5H6ClCrNO3
25 g
Moisture sensitive
PCC
215.56

Chemical Identifiers

26299-14-9
C5H6ClCrNO3
MFCD00013106
PCC
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Safety and Handling

Safety and Handling

GHS H Statement
H350-H272-H317
May cause cancer.
May intensify fire
oxidizer.
May cause an allergic skin reaction.

P201-P202-P210-P220-P221-P261-P272-P280g-P281-P302+P352-P308+P313-P333+P313-P363-P370+P378q-P501c

H272-H317-H350i

DOTInformation : Transport Hazard Class: 5.1; Packing Group: II; Proper Shipping Name: OXIDIZING SOLID, N.O.S.

EINECSNumber : 247-595-5

TSCA : Yes

Recommended Storage : Ambient temperatures

SDS
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