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Propargyl bromide, 80% in toluene, stab. with MgO

Catalog No. AAA16580AD
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Catalog No. AAA16580AD Supplier Thermo Scientific Chemicals Supplier No. A16580AD
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Description

CAS: 106-96-7 | C3H3Br | 118.961 g/mol

Propargyl bromide, 80% in toluene is used to prepare betulonic acid-peptide conjugates with anti-inflammatory activity and propargylic amines employed in enyne metathesis. It finds application in the propargylation of spiro ketones, allylic alcohols and enone complexes. In Barbier-type reaction, it reacts with aldehydes to give alkyne alcohols. It is actively involved in the synthesis of polyethylene glycol (PEG) and peptide-grafted polyesters.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Propargyl bromide, 80% in toluene is used to prepare betulonic acid-peptide conjugates with anti-inflammatory activity and propargylic amines employed in enyne metathesis. It finds application in the propargylation of spiro ketones, allylic alcohols and enone complexes. In Barbier-type reaction, it reacts with aldehydes to give alkyne alcohols. It is actively involved in the synthesis of polyethylene glycol (PEG) and peptide-grafted polyesters.

Solubility
Miscible with ethanol, ether, benzene, carbon tetrachloride and chloroform. Immiscible with water.

Notes
Light sensitive. Store in a cool place. Incompatible withbases, strong oxidizing agents, copper, peroxides, silver, silver oxides, mercury and mercury oxides.

Chemical Identifiers

CAS 106-96-7
Molecular Formula C3H3Br
Molecular Weight (g/mol) 118.961
MDL Number MFCD00000241
InChI Key YORCIIVHUBAYBQ-UHFFFAOYSA-N
Synonym propargyl bromide, 3-bromopropyne, 3-bromo-1-propyne, 1-propyne, 3-bromo, 2-propynyl bromide, propynyl bromide, 1-bromo-2-propyne, propyne, 3-bromo, gamma-bromoallylene, 1-brom-2-propin
PubChem CID 7842
IUPAC Name 3-bromoprop-1-yne
SMILES C#CCBr

Specifications

Melting Point -61°C
Density 1.335
Boiling Point 88°C to 90°C
Flash Point 3°C (37°F)
Refractive Index 1.494
Quantity 50 mL
UN Number UN2924
Beilstein 605309
Sensitivity Light sensitive
Solubility Information Miscible with ethanol,ether,benzene,carbon tetrachloride and chloroform. Immiscible with water.
Formula Weight 118.97
Concentration or Composition (by Analyte or Components) 80% in toluene
Chemical Name or Material Propargyl bromide, stabilized with MgO
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Safety and Handling

Hazard Category H225-H301-H304-H314-H335-H336-H361-H373
Hazard Statement GHS H Statement
H225-H300-H304-H361-H373-H314-H335-H336
Highly flammable liquid and vapour.
Fatal if swallowed.
May be fatal if swallowed and enters airways.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Causes severe skin burns and eye damage.
May cause respiratory irritation.
May cause drowsiness or dizziness.
Precautionary Statement P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c
DOTInformation Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.
EINECSNumber 203-447-1
RTECSNumber UK4375000
TSCA Yes
Recommended Storage Keep cold

RUO – Research Use Only