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Potassium tert-pentyloxide, 25% w/w in toluene

CAS: 41233-93-6 | C5H11KO | 126.24 g/mol

Supplier:  Thermo Scientific Chemicals L15111AU

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Catalog No. AAL15111AU


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Description

Description

Potassium tert-pentyloxide is a strong, hindered base used in combination with lithium diisopropyl amide to generate a superbase for the selective metallation of the aralkyl system at the 6-position of protected estradiols. It is used in organic synthesis, agrochemicals, pharmaceuticals, colorants and aroma chemicals. It acts as a catalyst in polymerization and isomerizations.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Potassium tert-pentyloxide is a strong, hindered base used in combination with lithium diisopropyl amide to generate a superbase for the selective metallation of the aralkyl system at the 6-position of protected estradiols. It is used in organic synthesis, agrochemicals, pharmaceuticals, colorants and aroma chemicals. It acts as a catalyst in polymerization and isomerizations.

Notes
Air and moisture sensitive. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and acids. Reacts violently with water.
Specifications

Specifications

Potassium tert-pentyloxide
0.87
C5H11KO
1000 mL
4149025
potassium 2-methylbutan-2-olate, potassium tert-amylate, potassium tert-pentoxide, potassium tert-pentylate, potassium tert-pentoxide solution, potassium 2-methyl-2-butoxide, 2-butanol, 2-methyl-, potassium salt, potassium tert-amyloxide, 2-butanol, 2-methyl-, potassium salt 1:1
[K+].CCC(C)(C)[O-]
126.24
126.24
41233-93-6
4°C (39°F)
MFCD00064808
UN2924
Air and moisture sensitive
ZRLVQFQTCMUIRM-UHFFFAOYSA-N
potassium;2-methylbutan-2-olate
23683543
25% w/w in toluene

Chemical Identifiers

41233-93-6
126.24
ZRLVQFQTCMUIRM-UHFFFAOYSA-N
23683543
[K+].CCC(C)(C)[O-]
C5H11KO
MFCD00064808
potassium 2-methylbutan-2-olate, potassium tert-amylate, potassium tert-pentoxide, potassium tert-pentylate, potassium tert-pentoxide solution, potassium 2-methyl-2-butoxide, 2-butanol, 2-methyl-, potassium salt, potassium tert-amyloxide, 2-butanol, 2-methyl-, potassium salt 1:1
potassium;2-methylbutan-2-olate
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Safety and Handling

Safety and Handling

GHS H Statement
H225-H304-H361-H373-H314-H336
Highly flammable liquid and vapor.
May be fatal if swallowed and enters airways.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Causes severe skin burns and eye damage.
May cause drowsiness or dizziness.

P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

H225-H304-H314-H335-H336-H361d-H373

DOTInformation : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.

EINECSNumber : 255-272-5

TSCA : Yes

Recommended Storage : Ambient temperatures; Store under Argon

SDS
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RUO – Research Use Only