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Phenylmagnesium bromide, 3M in ether
Grignard reagent | CAS: 100-58-3 | C6H5BrMg | 181.32 g/mol
$116.49 - $343.62
Chemical Identifiers
| CAS | 100-58-3 |
|---|---|
| Molecular Formula | C6H5BrMg |
| Molecular Weight (g/mol) | 181.32 |
| MDL Number | MFCD00000038 |
| InChI Key | ANRQGKOBLBYXFM-UHFFFAOYSA-M |
| Synonym | phenylmagnesium bromide, grignard reagent, magnesium, bromophenyl, magnesium, bromophenyl, phenylmagnesiumbromide, bromo phenyl magnesium, bromo phenyl magnesium, phenyl magnesium bromide, bromomagnesiobenzene, phenyhnagnesium bromide, phenyhnagnesium bromideShow More |
| PubChem CID | 66852 |
| SMILES | Br[Mg]C1=CC=CC=C1 |
Description
Grignard reagent Phenylmagnesium bromide is an important reagent called as Grignard reagent used in the synthesis of organic and oraganometallic reactions. It is used to prepare phenyl aryl sulphides, sulphoxides, and sulphones. It acts as a strong acid and Lewis acid and undergoes addition reaction with many unsaturated functional groups. It is involved in the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s, 1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol, o-substituted benzophenones and 6-benzyl-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol. In addition to this, it is used for the monalkylation of primary amines to get secondary amines.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Chemical Identifiers
| 100-58-3 | |
| 181.32 | |
| ANRQGKOBLBYXFM-UHFFFAOYSA-M | |
| 66852 |
| C6H5BrMg | |
| MFCD00000038 | |
| phenylmagnesium bromide, grignard reagent, magnesium, bromophenyl, magnesium, bromophenyl, phenylmagnesiumbromide, bromo phenyl magnesium, bromo phenyl magnesium, phenyl magnesium bromide, bromomagnesiobenzene, phenyhnagnesium bromide, phenyhnagnesium bromideShow More | |
| Br[Mg]C1=CC=CC=C1 |
Specifications
| 100-58-3 | |
| 1.14 g/mL | |
| C6H5BrMg | |
| 100 mL | |
| Air, light, and moisture sensitive; May form a Precipitate | |
| Miscible with terahydrofuran. | |
| Br[Mg]C1=CC=CC=C1 | |
| 181.32 | |
| 181.31 | |
| Liquid |
| Yellow to Brown | |
| Ether-like | |
| MFCD00000038 | |
| UN3399 | |
| phenylmagnesium bromide, grignard reagent, magnesium, bromophenyl, magnesium, bromophenyl, phmgbr, phenylmagnesiumbromide, phenyl magnesium bromide, phenyl magnesium bromide, phenylmagnesium bromide solution, 3.0 m in diethyl ether, phenyhnagnesium bromide, phenyhnagnesium bromide | |
| ANRQGKOBLBYXFM-UHFFFAOYSA-M | |
| bromo(phenyl)magnesium | |
| 66852 | |
| 3M in ether | |
| Phenylmagnesium bromide |
Safety and Handling
GHS H Statement
H224-H261-H314-H336
Extremely flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
May cause drowsiness or dizziness.
P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c
H224-H314-H335-H336
DOTInformation : Transport Hazard Class: 4.3; Packaging Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE
TSCA : Yes
Recommended Storage : Ambient temperatures; Store under Argon
RUO – Research Use Only