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  7. N-Methoxymethyl-N-(trimethylsilylmethyl)benzylamine, 94%

N-Methoxymethyl-N-(trimethylsilylmethyl)benzylamine, 94%

Catalog No. aal1941206
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Quantity:
1 g
5 g
Catalog No. Quantity
AAL1941206 5 g
AAL1941203 1 g
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Catalog No. AAL1941206

Supplier: Thermo Scientific Chemicals L1941206

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Description

CAS: 93102-05-7 | C13H23NOSi | 237.418 g/mol

N-Methoxymethyl-N-(trimethylsilylmethyl)benzylamine forms azomethine ylides which readily undergo [3+2] cycloaddition to α,β-unsaturated esters affording N-benzyl substituted pyrrolidines in good yields. It reacts with asymmetric 1,3-dipolar cycloadditions in the practical, large-scale synthesis of chiral pyrrolidines. It is used in the the synthesis of 3-carboxy-1-azabicyclo[2.2.1]heptane derivatives, an important class of physiologically active compounds.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
N-Methoxymethyl-N-(trimethylsilylmethyl)benzylamine forms azomethine ylides which readily undergo [3+2] cycloaddition to α,ß-unsaturated esters affording N-benzyl substituted pyrrolidines in good yields. It reacts with asymmetric 1,3-dipolar cycloadditions in the practical, large-scale synthesis of chiral pyrrolidines. It is used in the the synthesis of 3-carboxy-1-azabicyclo[2.2.1]heptane derivatives, an important class of physiologically active compounds.

Solubility
Soluble in chloroform, ethyl acetate.

Notes
Moisture & Light Sensitive. Store away from oxidizing agents.

Chemical Identifiers

CAS 93102-05-7
Molecular Formula C13H23NOSi
Molecular Weight (g/mol) 237.418
MDL Number MFCD00674005
InChI Key RPZAAFUKDPKTKP-UHFFFAOYSA-N
Synonym n-methoxymethyl-n-trimethylsilylmethyl benzylamine, n-benzyl-1-methoxy-n-trimethylsilyl methyl methanamine, benzyl methoxymethyl trimethylsilyl methyl amine, benzyl-methoxymethyl-trimethylsilanylmethyl-amine, n-benzyl-n-methoxymethyl-n-trimethylsilylmethylamine, n-benzyl-n-methoxymethyl trimethylsilylmethylamine, n-methoxymethyl phenyl-n-trimethylsilyl methyl methanamine, n-methoxymethyl-n-trimethylsilyl methyl phenyl, n-methoxymethyl-n-trimethylsilylmethyl-benzylamine
PubChem CID 353442
IUPAC Name N-(methoxymethyl)-1-phenyl-N-(trimethylsilylmethyl)methanamine
SMILES COCN(CC1=CC=CC=C1)C[Si](C)(C)C

Specifications

Density 0.928
Boiling Point 76°C (0.3 mmHg)
Flash Point 66°C (150°F)
Refractive Index 1.492
Quantity 5 g
Beilstein 4311216
Sensitivity Light and moisture sensitive
Solubility Information Soluble in chloroform,ethyl acetate.
Formula Weight 237.42
Percent Purity 94%
Chemical Name or Material N-Methoxymethyl-N-(trimethylsilylmethyl)benzylamine
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Safety and Handling

Hazard Category H227-H315-H319-H335
Hazard Statement GHS H Statement
H315-H319-H335-H227
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Combustible liquid.
Precautionary Statement P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c
EINECSNumber 000-000-0
TSCA No
Recommended Storage Keep cold; Store under Nitrogen

RUO – Research Use Only