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mu-Chloro-mu-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene, Thermo Scientific Chemicals

$129.19 - $511.63

Chemical Identifiers

CAS 67719-69-1
Molecular Formula C13H18AlClTi
MDL Number MFCD00151575
Synonym Tebbe Reagent
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Products 2
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AA44506AA
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Thermo Scientific Chemicals
044506AA
5 mL
Each for $129.19
 
AA44506AC
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Thermo Scientific Chemicals
044506AC
25 mL
Each for $511.63
 
Description

Description

μ-Chloro-μ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum is used in organic synthesis for carbonyl methylenation, A versatile methylenation reagent for the conversion of ketones and aldehydes to olefins, it offers facile reaction with hindered ketones and allows the conversion of esters to vinyl ethers. Tebbe reagent can be used to olefinate aldehydes, to methylenate a chiral polyhydroxyketone with high diasteroselctivity.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

67719-69-1
C13H18AlClTi
MFCD00151575
Tebbe Reagent

Specifications

67719-69-1
0.927 g/mL
C13H18AlClTi
5 mL
Air and moisture sensitive
Tebbe Reagent
284.62
mu-Chloro-mu-methylenebis (cyclopentadienyl)titaniumdimethylaluminum
Brown-Red
1°C (34°F)
MFCD00151575
UN3399
14,9091
Soluble in toluene,benzene,dichloromethane. Insoluble in water.
Liquid
Safety and Handling

Safety and Handling

GHS H Statement
H225-H261-H304-H361-H373-H314-H336
Highly flammable liquid and vapor.
In contact with water releases flammable gas.
May be fatal if swallowed and enters airways.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Causes severe skin burns and eye damage.
May cause drowsiness or dizziness.

P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

H225-H304-H314-H335-H336-H361d-H373

DOTInformation : Hazard Class: 3; Packaging Group: II

TSCA : No

Recommended Storage : Ambient temperatures; Store under Nitrogen

SDS
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RUO – Research Use Only