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mu-Chloro-mu-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene
Description
μ-Chloro-μ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum is used in organic synthesis for carbonyl methylenation, A versatile methylenation reagent for the conversion of ketones and aldehydes to olefins, it offers facile reaction with hindered ketones and allows the conversion of esters to vinyl ethers. Tebbe reagent can be used to olefinate aldehydes, to methylenate a chiral polyhydroxyketone with high diasteroselctivity.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Specifications
Specifications
| Color | Brown-Red |
| Density | 0.927 g/mL |
| Flash Point | 1°C (34°F) |
| Quantity | 5 mL |
| UN Number | UN3399 |
| Sensitivity | Air and moisture sensitive |
| Merck Index | 14,9091 |
| Solubility Information | Soluble in toluene,benzene,dichloromethane. Insoluble in water. |
| Formula Weight | 284.62 |
| Physical Form | Liquid |
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Safety and Handling
| Hazard Category | H225-H304-H314-H335-H336-H361d-H373 |
| Hazard Statement | GHS H Statement H225-H261-H304-H361-H373-H314-H336 Highly flammable liquid and vapor. In contact with water releases flammable gas. May be fatal if swallowed and enters airways. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Causes severe skin burns and eye damage. May cause drowsiness or dizziness. |
| Precautionary Statement | P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c |
| DOTInformation | Hazard Class: 3; Packaging Group: II |
| TSCA | No |
| Recommended Storage | Ambient temperatures; Store under Nitrogen |
RUO – Research Use Only