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Lithium tert-butoxide, 99.9% (metals basis)
CAS: 1907-33-1 | C4H9LiO | 80.055 g/mol
$187.92 - $765.97
Chemical Identifiers
| CAS | 1907-33-1 |
|---|---|
| Molecular Formula | C4H9LiO |
| Molecular Weight (g/mol) | 80.055 |
| MDL Number | MFCD00050479 |
| InChI Key | LZWQNOHZMQIFBX-UHFFFAOYSA-N |
| Synonym | lithium tert-butoxide, lithium 2-methylpropan-2-olate, tert-butoxylithium, lithium tert-butylate, lithium tert-butanolate, tert-butyl alcohol, lithium salt, lithium t-butoxide, 2-methyl-2-propanol lithium salt, 2-propanol, 2-methyl-, lithium salt, lithium 1+ ion 2-methylpropan-2-olateShow More |
| PubChem CID | 23664764 |
| IUPAC Name | lithium;2-methylpropan-2-olate |
| SMILES | [Li+].CC(C)(C)[O-] |
Description
Lithium tert-butoxide is a mild base used in organic synthesis. It is involved in the alfa-alkylation reaction of ketones with primary alcohols. It is utilized as a catalyst in the reduction of ketones to the corresponding secondary alcohols. It acts as lithium source utilized in the preparation of LixTiyOz thin films. Further, it is used in conjunction with organometallic reagents/catalysts to modify their reactivity and selectivity.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Chemical Identifiers
| 1907-33-1 | |
| 80.055 | |
| LZWQNOHZMQIFBX-UHFFFAOYSA-N | |
| 23664764 | |
| [Li+].CC(C)(C)[O-] |
| C4H9LiO | |
| MFCD00050479 | |
| lithium tert-butoxide, lithium 2-methylpropan-2-olate, tert-butoxylithium, lithium tert-butylate, lithium tert-butanolate, tert-butyl alcohol, lithium salt, lithium t-butoxide, 2-methyl-2-propanol lithium salt, 2-propanol, 2-methyl-, lithium salt, lithium 1+ ion 2-methylpropan-2-olateShow More | |
| lithium;2-methylpropan-2-olate |
Specifications
| 1907-33-1 | |
| White to Cream | |
| C4H9LiO | |
| MFCD00050479 | |
| UN3206 | |
| Air and moisture sensitive | |
| Soluble in toluene,hexane,tetrahydrofuran and methyl tert-butyl ether. | |
| [Li+].CC(C)(C)[O-] | |
| 80.055 | |
| 80.06 | |
| Powder | |
| (metals basis) |
| ∼150°C (decomposition) | |
| Odorless | |
| (CH3)3COLi | |
| 10 g | |
| 3620018 | |
| lithium tert-butoxide, lithium 2-methylpropan-2-olate, tert-butoxylithium, lithium tert-butylate, lithium tert-butanolate, tert-butyl alcohol, lithium salt, lithium t-butoxide, 2-methyl-2-propanol lithium salt, 2-propanol, 2-methyl-, lithium salt, lithium 1+ ion 2-methylpropan-2-olate | |
| LZWQNOHZMQIFBX-UHFFFAOYSA-N | |
| lithium;2-methylpropan-2-olate | |
| 23664764 | |
| 99.9% | |
| Lithium tert-butoxide |
Safety and Handling
GHS H Statement
H251-H314-H302
Self-heating: may catch fire.
Causes severe skin burns and eye damage.
Harmful if swallowed.
P210-P240-P241-P260-P264b-P270-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c
H228-H302-H314
DOTInformation : Hazard Class: 4.1; Packaging Group: II
EINECSNumber : 217-611-5
RTECSNumber : UB8520000
TSCA : Yes
Recommended Storage : Ambient temperatures; Store under Nitrogen
RUO – Research Use Only