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Lead(IV) acetate, 96% (dry wt.), stab. with 5-10% glacial acetic acid, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals A155510B

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Catalog No. AAA155510B



Description

Description

Lead(IV) acetate is an important oxidizing agent and a source of acetyloxy group used in organic synthesis. For example, 1,4-dioxene is prepared from dioxane involving 2-acetoxy-1,4-dioxane as an intermediate. Similarly, it is used for the preparation of bis(trifluoromethyl)diazomethane from hexafluoroacetone hydrazone. It also reacts with alkenes, alcohols having a delta-proton and di-n-butyl d-tartrate to get gamma-lactones, cyclic ethers and n-butyl glyoxylate respectively. It induces the cleavage of 1,2-diols to the corresponding aldehydes or ketones. It is actively involved in the Kochi reaction for the decarboxylation of carboxylic acids to alkyl halides and used as an alternative reagent to bromine in the Hofmann rearrangement.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Lead(IV) acetate is an important oxidizing agent and a source of acetyloxy group used in organic synthesis. For example, 1,4-dioxene is prepared from dioxane involving 2-acetoxy-1,4-dioxane as an intermediate. Similarly, it is used for the preparation of bis(trifluoromethyl)diazomethane from hexafluoroacetone hydrazone. It also reacts with alkenes, alcohols having a delta-proton and di-n-butyl d-tartrate to get gamma-lactones, cyclic ethers and n-butyl glyoxylate respectively. It induces the cleavage of 1,2-diols to the corresponding aldehydes or ketones. It is actively involved in the Kochi reaction for the decarboxylation of carboxylic acids to alkyl halides and used as an alternative reagent to bromine in the Hofmann rearrangement.

Solubility
Soluble in water, ethanol, chloroform, benzene, nitrobenzene, tetrachloroethane, nitric acid, hot acetic acid and hydrochloric acid.

Notes
Air and moisture sensitive. Store in cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with alcohols, strong acids and strong reducing agents.
Specifications

Specifications

Lead(IV) acetate
546-67-8
2.28
C8H16O8Pb
MFCD00008693
UN1616
Moisture sensitive
lead iv acetate
NVTAREBLATURGT-UHFFFAOYSA-N
acetic acid;lead
50931538
96%
stabilized with 5 to 10% glacial acetic acid
175°C
(dry wt.)
Pb(OOCCH3)4
1000 g
3595640
14,5423
Soluble in water,ethanol,chloroform,benzene,nitrobenzene,tetrachloroethane,nitric acid,hot acetic acid and hydrochloric acid.
CC(=O)O.CC(=O)O.CC(=O)O.CC(=O)O.[Pb]
447.408
443.37

Chemical Identifiers

546-67-8
447.408
NVTAREBLATURGT-UHFFFAOYSA-N
50931538
CC(=O)O.CC(=O)O.CC(=O)O.CC(=O)O.[Pb]
C8H16O8Pb
MFCD00008693
lead iv acetate
acetic acid;lead
Safety and Handling

Safety and Handling

GHS H Statement
H360-H373-H302-H332-H201
May damage fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Harmful if swallowed.
Harmful if inhaled.
Explosive; mass explosion hazard.

P201-P202-P260-P264b-P270-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c

H302+H332-H314-H335-H350-H360Df-H373

DOTInformation : Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: LEAD ACETATE

EINECSNumber : 208-908-0

RTECSNumber : AI5300000

TSCA : Yes

Recommended Storage : Ambient temperatures; Store under Nitrogen

SDS
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