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  7. Iron(III) nitrate nonahydrate, ACS, 98.0-101.0%

Iron(III) nitrate nonahydrate, ACS, 98.0-101.0%

Catalog No. p-4407482
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500 g
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AA3331536 500 g
AA33315A3 2 kg
AA33315F7 5 x 2 kg
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Catalog No. AA3331536 Supplier Thermo Scientific Chemicals Supplier No. 03331536
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Description

CAS: 7782-61-8 | FeH18N3O18 | 403.99 g/mol

It is used as catalyst for the synthesis of sodium amide from sodium and ammonia, and for etching of silver and silver alloys. Ferric nitrate is used in the synthesis of organically templated iron phosphates, and acts as an efficient catalyst in enamination of beta dicarbonyl compounds to beta enaminones. Ferric nitrate impregnated clays are useful as oxidizing agents. Clayfen, produced from ferric nitrate and montmorillonite, is used for the oxidation of thiols to disulfide, and alcohols to aldehydes. Ferric nitrate is useful for regio- and stereo-selective nitration of various aromatic, aliphatic, and heteroaromatic olefins. This reaction provides nitroolefins with excellent E-selectivity. With Keggin-type heteropoly acids, it selectively oxidizes various hydroxy groups.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

CAS 7782-61-8
Molecular Formula FeH18N3O18
Molecular Weight (g/mol) 403.99
MDL Number MFCD00149708
InChI Key SZQUEWJRBJDHSM-UHFFFAOYSA-N
Synonym ferric nitrate nonahydrate, iron iii nitrate nonahydrate, unii-vmx4uop3vn, ferric nitrate, nonahydrate, iron iii nitrate, vmx4uop3vn, iron, reference standard solution, ferricnitratenonahydrate, nitric acid, iron 3+ salt, nonahydrate, iron iii nitrate hydrate
PubChem CID 16211566
IUPAC Name iron(3+) nonahydrate trinitrate
SMILES O.O.O.O.O.O.O.O.O.[Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

Specifications

Boiling Point 125°C (decomposition)
Melting Point 47°C
Color Purple
Physical Form Crystalline
Quantity 500 g
Assay Percent Range 98.0 to 101.0%
Solubility Information Freely soluble in water,alcohol,acetone. Slightly soluble in cold and concentrated HNO3Soluble in water,alcohol and acetone.
Formula Weight 403.99 (241.86 Anhydrous)
Grade ACS
Odor Acidic
Sensitivity Moisture sensitive
Appearance Pale purple
Density 1.684 g/cm3
Chemical Name or Material Iron(III) nitrate nonahydrate, For ACS analysis
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Safety and Handling

Hazard Category H272-H315-H319-H335
Precautionary Statement P210-P220-P221-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c
DOTInformation DOT Class: 5.1, Packing Group: III
EINECSNumber 233-899-5
RTECSNumber NO7175000
TSCA Yes
Recommended Storage Ambient temperatures; Store under Nitrogen

RUO – Research Use Only