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Glycine tert-butyl ester, 97%

CAS: 6456-74-2 | C6H13NO2 | 131.175 g/mol

Supplier:  Thermo Scientific Chemicals L1625803

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Catalog No. AAL1625803


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Description

Description

Glycine tert-butyl ester is used in the preparation of Schiff base by reacting with benzophenone. The resultant Schiff base undergoes asymmetric alkylation with arylmethyl bromides in the presence of O-allyl-N-(9-anthracenylmethyl)cinchonidinium bromide as chiral phase transfer catalyst to give guanidine-containing pentacyclic compound.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Glycine tert-butyl ester is used in the preparation of Schiff base by reacting with benzophenone. The resultant Schiff base undergoes asymmetric alkylation with arylmethyl bromides in the presence of O-allyl-N-(9-anthracenylmethyl)cinchonidinium bromide as chiral phase transfer catalyst to give guanidine-containing pentacyclic compound.

Solubility
Miscible with acetone and methanol. Slightly miscible with ehtanol. Immiscible with water.

Notes
Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.
Specifications

Specifications

Glycine tert-butyl ester
29°C to 31°C (2mmHg)
1.424
2039000
Miscible with acetone and methanol. Slightly miscible with ehtanol. Immiscible with water.
CC(C)(C)OC(=O)CN
tert-butyl 2-aminoacetate
131.175
131.18
97%
6456-74-2
C6H13NO2
MFCD00038194
tert-butyl glycinate, glycine tert-butyl ester, glycine, 1,1-dimethylethyl ester, tert-butyl aminoacetate, h-gly-otbu, t-butyl glycinate, glycin-tert-butyl ester, 1,1-dimethylethyl glycinate, glycine t-butyl ester, aminoacetic acid tert-butyl ester
SJMDMGHPMLKLHQ-UHFFFAOYSA-N
0.96
1 g
151417
Air sensitive

Chemical Identifiers

6456-74-2
131.175
SJMDMGHPMLKLHQ-UHFFFAOYSA-N
151417
CC(C)(C)OC(=O)CN
C6H13NO2
MFCD00038194
tert-butyl glycinate, glycine tert-butyl ester, glycine, 1,1-dimethylethyl ester, tert-butyl aminoacetate, h-gly-otbu, t-butyl glycinate, glycin-tert-butyl ester, 1,1-dimethylethyl glycinate, glycine t-butyl ester, aminoacetic acid tert-butyl ester
tert-butyl 2-aminoacetate
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Safety and Handling

Safety and Handling

TSCA : No

Recommended Storage : Keep cold; Store under Argon

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