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Ethyl nitroacetate, 97%

CAS: 626-35-7 | C4H7NO4 | 133.103 g/mol

$45.37 - $1454.62

Chemical Identifiers

CAS 626-35-7
Molecular Formula C4H7NO4
Molecular Weight (g/mol) 133.103
MDL Number MFCD00007403
InChI Key FTKASJMIPSSXBP-UHFFFAOYSA-N
Synonym ethyl nitroacetate, nitroacetic acid ethyl ester, acetic acid, nitro-, ethyl ester, nitro ethyl acetate, ethylnitroacetate, acetic acid, 2-nitro-, ethyl ester, ethylnitroacetat, ethyinitroacetate, ethyl-2-nitroacetate, zlchem 269
PubChem CID 69379
IUPAC Name ethyl 2-nitroacetate
SMILES CCOC(=O)C[N+](=O)[O-]
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AAA1443303
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Thermo Scientific Chemicals
A1443303
1 g
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AAA1443306
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A1443306
5 g
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AAA1443314
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A1443314
25 g
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AAA1443322
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A1443322
100 g
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Description

Description

Ethyl nitroacetate has been used in the synthesis of γ-oxoacids via Michael addition reaction with α,β-unsaturated ketones, fuctionalization of C4-position on pyrimidine and C6-position on 2-deoxyguanosine to produce novel nucleosides, facile synthesis of α,α-diisobutylglycine, synthesis of DL-4,4-difluoroglutamic acid. It is also used as an intermediate in the preparation of unsubstituted amino acids.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Ethyl nitroacetate has been used in the synthesis of γ-oxoacids via Michael addition reaction with α,β-unsaturated ketones, fuctionalization of C4-position on pyrimidine and C6-position on 2′-deoxyguanosine to produce novel nucleosides, facile synthesis of α,α-diisobutylglycine, synthesis of DL-4,4-difluoroglutamic acid. It is also used as an intermediate in the preparation of unsubstituted amino acids.

Solubility
Slightly soluble in water. Soluble in chloroform and ethyl acetate.

Notes
Store away from bases and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
Specifications

Chemical Identifiers

626-35-7
133.103
FTKASJMIPSSXBP-UHFFFAOYSA-N
69379
CCOC(=O)C[N+](=O)[O-]
C4H7NO4
MFCD00007403
ethyl nitroacetate, nitroacetic acid ethyl ester, acetic acid, nitro-, ethyl ester, nitro ethyl acetate, ethylnitroacetate, acetic acid, 2-nitro-, ethyl ester, ethylnitroacetat, ethyinitroacetate, ethyl-2-nitroacetate, zlchem 269
ethyl 2-nitroacetate

Specifications

626-35-7
93°C to 95°C (10 mmHg)
Weak
1.424
MFCD00007403
1210027
Slightly soluble in water. Soluble in chloroform and ethyl acetate.
CCOC(=O)C[N+](=O)[O-]
133.103
133.11
Ethyl nitroacetate
1.202
92°C (197°F)
C4H7NO4
O2NCH2CO2CH2CH3
1 g
ethyl nitroacetate, nitroacetic acid ethyl ester, acetic acid, nitro-, ethyl ester, nitro ethyl acetate, ethylnitroacetate, acetic acid, 2-nitro-, ethyl ester, ethylnitroacetat, ethyinitroacetate, ethyl-2-nitroacetate, zlchem 269
FTKASJMIPSSXBP-UHFFFAOYSA-N
ethyl 2-nitroacetate
69379
97%
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Safety and Handling

Safety and Handling

GHS H Statement
H315-H319-H227
Causes skin irritation.
Causes serious eye irritation.
Combustible liquid.

P210-P264b-P280-P302+P352-P305+P351+P338-P332+P313-P362-P370+P378q-P501c

H227-H315-H319

EINECSNumber : 210-944-7

RTECSNumber : AJ1074000

TSCA : Yes

Recommended Storage : Ambient temperatures

SDS
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RUO – Research Use Only