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Diethyl diallylmalonate, 97+%
CAS: 3195-24-2 | C13H20O4 | 240.299 g/mol
Supplier: Thermo Scientific Chemicals A1246030
Description
Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke?s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsDiethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke′s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.
Solubility
Sparingly Soluble in water. (0.72 g/L) (25°C)
Notes
Store under cool dry place. Ensure good ventilation.
Specifications
| Diethyl diallylmalonate | |
| 0.993 | |
| >110°C (230°F) | |
| 1.446 | |
| 250 g | |
| diethyl diallylmalonate, diethyl 2,2-diallylmalonate, diallylmalonic acid diethyl ester, propanedioic acid, di-2-propenyl-, diethyl ester, 1,3-diethyl 2,2-bis prop-2-en-1-yl propanedioate, diethyl 2,2-diprop-2-enylpropane-1,3-dioate, diethyldiallylmalonate, malonic acid, diallyl-, diethyl ester, diethyl2,2-diallylmalonate, acmc-1cp69 | |
| LYUUVYQGUMRKOV-UHFFFAOYSA-N | |
| diethyl 2,2-bis(prop-2-enyl)propanedioate | |
| 76664 | |
| 98% |
| 3195-24-2 | |
| 242°C to 244°C | |
| C13H20O4 | |
| MFCD00009126 | |
| 1790529 | |
| Sparingly Soluble in water. (0.72g/L) (25°C) | |
| CCOC(=O)C(CC=C)(CC=C)C(=O)OCC | |
| 240.299 | |
| 240.3 |
Chemical Identifiers
| 3195-24-2 | |
| 240.299 | |
| LYUUVYQGUMRKOV-UHFFFAOYSA-N | |
| diethyl 2,2-bis(prop-2-enyl)propanedioate |
| C13H20O4 | |
| MFCD00009126 | |
| 76664 | |
| CCOC(=O)C(CC=C)(CC=C)C(=O)OCC |
Safety and Handling
GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
H315-H319-H335
EINECSNumber : 221-696-4
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only