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  7. cis-Cyclooctene, 95%, stab.

cis-Cyclooctene, 95%, stab.

Catalog No. p-7021225
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Quantity:
100 mL
250 mL
50 mL
500 mL
Catalog No. Quantity
AAA13477AD 50 mL
AAA13477AE 100 mL
AAA13477AK 250 mL
AAA13477AP 500 mL
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Catalog No. AAA13477AD

Supplier: Thermo Scientific Chemicals A13477AD

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Description

CAS: 931-87-3 | C8H14 | 110.20 g/mol

cis-Cyclooctene is used as a displaced ligand in chlorobis(cyclooctene)rhodium dimer and chlorobis(cyclooctene)iridium dimer in organometallic chemistry. It acts as a monomer used in synthetic chemistry. It is used to prepare 1-chloro-4-(trichloromethyl) cyclooctane by reaction with carbon tetrachloride using dichlorotris(triphenylphosphine) ruthenium(II) as a catalyst. Further, it is used to study the alkenes chemisorbed on silicon(100) by scanning tunneling microscopy.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
cis-Cyclooctene is used as a displaced ligand in chlorobis(cyclooctene)rhodium dimer and chlorobis(cyclooctene)iridium dimer in organometallic chemistry. It acts as a monomer used in synthetic chemistry. It is used to prepare 1-chloro-4-(trichloromethyl) cyclooctane by reaction with carbon tetrachloride using dichlorotris(triphenylphosphine) ruthenium(II) as a catalyst. Further, it is used to study the alkenes chemisorbed on silicon(100) by scanning tunneling microscopy.

Solubility
Miscible with alcohol and ether. Immiscible with water.

Notes
Air sensitive. Incompatible with strong oxidizing agents.

Chemical Identifiers

CAS 931-87-3
Molecular Formula C8H14
Molecular Weight (g/mol) 110.20
MDL Number MFCD00001753
InChI Key URYYVOIYTNXXBN-UPHRSURJSA-N
Synonym cis-cyclooctene, z-cyclooctene, cyclooctene, z, cyclooctene, 1z, cyclooct-1-ene, e-cyclooctene, 1-cyclooctene #, 1z-cyclooctene, 7z-cyclooctene, ar,e-cyclooctene
PubChem CID 638079
SMILES C1CCC\C=C/CC1

Specifications

Melting Point -16°C
Density 0.848
Boiling Point 145°C to 146°C
Flash Point 25°C (77°F)
Odor Recognizable
Refractive Index 1.47
Quantity 50 mL
UN Number UN3295
Beilstein 1280166
Sensitivity Air Sensitive
Solubility Information Miscible with alcohol and ether. Immiscible with water.
IUPAC Name (Z)-cyclooctene
Formula Weight 110.2
Percent Purity 95%
Chemical Name or Material cis-Cyclooctene, stabilized
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Safety and Handling

Hazard Category H226-H304
Hazard Statement GHS H Statement
H304-H226
May be fatal if swallowed and enters airways.
Flammable liquid and vapour.
Precautionary Statement P210-P233-P240-P241-P242-P243-P280-P301+P310-P303+P361+P353-P331-P370+P378q-P501c
DOTInformation Transport Hazard Class: 3; Packing Group: III; Proper Shipping Name: HYDROCARBONS, LIQUID, N.O.S.
EINECSNumber 213-243-4
TSCA Yes
Recommended Storage Ambient temperatures

RUO – Research Use Only