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Chromyl chloride, 99.99% (metals basis)
CAS: 14977-61-8 | Cl2CrH4O2 | 158.926 g/mol
Supplier: Thermo Scientific Chemicals 04051709
Description
Highly spin-polarized chromium dioxide (CrO2) thin films were deposited on 100 TiO2 substrates by chemical vapor deposition using chromyl chloride as a precursor. Chromyl chloride (Cr02C12) reacts with cyclohexane solvent at 75 OC to give a dark precipitate along with chlorocyclohexane and a small amount of cyclohexene (in 10.0 and ca. 0.3% yields based on chromium). Chromyl chloride, CrO2C12, oxidizes cyclooctane, isobutane, and toluene under mild conditions (25-60 C). The reactions give chlorinated products (chlorocyclooctane, tert- butyl chloride, and benzyl chloride) and a dark chromium-containing precipitate. Used for Organic oxidations and chlorination, chromium coordination complexes, catalyst for polymerization of olefins. Chromyl chloride in carbon tetrachloride solution reacts in the cold with cyclohexene, cyclopentene, and 1-hexene to give the various isomeric chlorohydrins as the major products.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
- Organic oxidations and chlorination, chromium coordination complexes, catalyst for polymerization of olefins
Specifications
| 117°C | |
| -96.5°C | |
| Liquid | |
| (metals basis) | |
| MFCD00010951 | |
| 14,2248 | |
| Soluble in carbon tetrachloride,carbon disulfide,benzene,nitrobenzene,chloroform,and POCL3. Insoluble in water(Reacts). | |
| O.O.[Cl-].[Cl-].[Cr+2] | |
| 158.926 | |
| 154.9 | |
| Pungent, makes eyes water | |
| 1.911g/mL |
| Chromyl chloride | |
| 14977-61-8 | |
| 10 g | |
| Cl2CrH4O2 | |
| UN1758 | |
| chromyl chloride | |
| HOCPFYCTFLRIAK-UHFFFAOYSA-L | |
| chromium(2+);dichloride;dihydrate | |
| 101943071 | |
| 99.99% | |
| Moisture sensitive |
Chemical Identifiers
| 14977-61-8 | |
| 158.926 | |
| HOCPFYCTFLRIAK-UHFFFAOYSA-L | |
| 101943071 | |
| O.O.[Cl-].[Cl-].[Cr+2] |
| Cl2CrH4O2 | |
| MFCD00010951 | |
| chromyl chloride | |
| chromium(2+);dichloride;dihydrate |
Safety and Handling
GHS H Statement
H272-H340-H350-H314-H318-H317
May intensify fire
oxidizer.
May cause genetic defects.
May cause cancer.
Causes severe skin burns and eye damage.
Causes serious eye damage.
May cause an allergic skin reaction.
P201-P202-P210-P220-P221-P260-P264b-P272-P280g-P281-P283-P301+P330+P331-P302+P352-P304+P340-P305+P351+P338-P306+P360-P310-P333+P313-P353-P363-P370+P378q-P371+P380+P375-P501c
H271-H314-H317-H340-H350i
DOTInformation : Transport Hazard Class: 8; Packing Group: I; Proper Shipping Name: CHROMIUM OXYCHLORIDE
EINECSNumber : 239-056-8
RTECSNumber : GB5775000
TSCA : Yes
Recommended Storage : Ambient temperatures
RUO – Research Use Only