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  6. Thermo Scientific Chemicals Burgess Reagent, 96%

Thermo Scientific Chemicals Burgess Reagent, 96%

Catalog No. p-7048046
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AAL2015503 1 g
AAL2015506 5 g
AAL2015514 25 g
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Catalog No. AAL2015503 Supplier Thermo Scientific Chemicals Supplier No. L2015503
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Description

CAS: 29684-56-8 | C8H18N2O4S | 238.30 g/mol

Burgess reagent is a selective dehydrating reagent used in organic synthesis. It is used to convert secondary and tertiary alcohol, with an adjacent proton, into alkenes. Burgess reagent is also utilized to promote great synthetic values in medicinal chemistry. It has been used in dehydration of primary amides, formamides and primary nitroalkanes to generate nitriles, isocyanides and nitrile oxides respectively. It forms urethanes when it reacts with primary alcohols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Burgess reagent is a selective dehydrating reagent used in organic synthesis. It is used to convert secondary and tertiary alcohol, with an adjacent proton, into alkenes. Burgess reagent is also utilized to promote great synthetic values in medicinal chemistry. It has been used in dehydration of primary amides, formamides and primary nitroalkanes to generate nitriles, isocyanides and nitrile oxides respectively. It forms urethanes when it reacts with primary alcohols.

Solubility
Soluble in organic solvents.

Notes
Store in cool place. Moisture sensitive. Incompatible with strong oxidizing agents.

Chemical Identifiers

CAS 29684-56-8
Molecular Formula C8H18N2O4S
Molecular Weight (g/mol) 238.30
MDL Number MFCD00077815
InChI Key YSHOWEKUVWPFNR-UHFFFAOYSA-N
Synonym methoxycarbonylsulfamoyl triethylammonium hydroxide, burgess reagent, carbomethoxysulfamoyltriethylammonium hydroxide, methoxycarbonylsulfamoyltriethylammonium hydroxide, methoxycarbonylsulphamoyltriethylammonium hydroxide, methoxy-carbonylsulfamoyltriethylammonium hydroxide, methoxycarbonylsulfa-moyl-triethylammonium hydroxide, methoxycarbonylsulphamoyl-triethylammonium hydroxide
PubChem CID 11032497
SMILES CC[N+](CC)(CC)S(=O)(=O)[N-]C(=O)OC

Specifications

Melting Point 72°C to 82°C
Quantity 1 g
Beilstein 1432131
Sensitivity Moisture sensitive
Solubility Information Soluble in organic solvents.
IUPAC Name (methoxycarbonyl)[(triethylazaniumyl)sulfonyl]azanide
Formula Weight 238.3
Percent Purity 96%
Chemical Name or Material Burgess Reagent

Safety and Handling

Hazard Category H315-H319-H335
Hazard Statement GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
TSCA No
Recommended Storage Store at -20°C

RUO – Research Use Only