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Boron trifluoride diethyl etherate, 98+%

Catalog No. p-7022471
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AAA15275AE 100 mL
AAA15275AP 500 mL
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Catalog No. AAA15275AE Supplier Thermo Scientific Chemicals Supplier No. A15275AE
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CAS: 109-63-7 | C4H10BF3O | 141.93 g/mol

Boron trifluoride diethyl etherate is used as a Lewis acid catalyst in Mukaiyama aldol addition, alkylation, acetylation, isomerization, dehydrations and condensation reactions. It is involved in the prepattion of polyethers in polymerization reactions. As a catalyst, it is used in the preparation of cyclopentyl- and cycloheptyl[b]indoles and other diborane. It is also used in sensitive neutron detectors in ionization chambers as well as monitoring radiation levels in earth’s atmosphere.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Boron trifluoride diethyl etherate is used as a Lewis acid catalyst in Mukaiyama aldol addition, alkylation, acetylation, isomerization, dehydrations and condensation reactions. It is involved in the prepattion of polyethers in polymerization reactions. As a catalyst, it is used in the preparation of cyclopentyl- and cycloheptyl[b]indoles and other diborane. It is also used in sensitive neutron detectors in ionization chambers as well as monitoring radiation levels in earth’s atmosphere.

Solubility
Miscible with ether and alcohol.

Notes
Moisture sensitive. Store in cool place. Recommended to use under inet atomosphere. Incompatible with metals, acids, bases, alcohols, alkali metals, oxidizing agents and water. Reacts violently with water.

Chemical Identifiers

CAS 109-63-7
Molecular Formula C4H10BF3O
Molecular Weight (g/mol) 141.93
MDL Number MFCD00013194
InChI Key KZMGYPLQYOPHEL-UHFFFAOYSA-N
Synonym Boron trifluoride etherate; Boron fluoride-ether
PubChem CID 8000
IUPAC Name ethoxyethane;trifluoroborane
SMILES FB(F)F.CCOCC

Specifications

Melting Point -60°C
Density 1.13
Boiling Point 125°C to 126°C
Flash Point 47°C (116°F)
Odor Acrid
Refractive Index 1.344
Linear Formula BF3€O(CH2CH3)2
Quantity 100 mL
UN Number UN2604
Beilstein 3909607
Sensitivity Moisture sensitive
Merck Index 14,1350
Solubility Information Miscible with ether and alcohol.
Formula Weight 141.93
Percent Purity ≥98%
Chemical Name or Material Boron trifluoride diethyl etherate
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Hazard Category H226-H314-H332-H372
Hazard Statement GHS H Statement
H331-H372-H314-H318-H226-H302
Toxic if inhaled.
Causes damage to organs through prolonged or repeated exposure.
Causes severe skin burns and eye damage.
Causes serious eye damage.
Flammable liquid and vapour.
Harmful if swallowed.
Precautionary Statement P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c
DOTInformation Transport Hazard Class: 8; Packing Group: I; Proper Shipping Name: BORON TRIFLUORIDE DIETHYL ETHERATE
EINECSNumber 203-689-8
TSCA Yes
Recommended Storage Ambient temperatures; Store under Nitrogen

RUO – Research Use Only