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  6. Borane-dimethyl sulfide complex, 2M in toluene, packaged under Argon in resealable ChemSeal™ bottles

Borane-dimethyl sulfide complex, 2M in toluene, packaged under Argon in resealable ChemSeal™ bottles

Catalog No. p-7058658
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Quantity:
100 mL
500 mL
Catalog No. Quantity
AA42963AE 100 mL
AA42963AP 500 mL
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Catalog No. AA42963AE

Supplier: Thermo Scientific Chemicals 042963AE

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Description

CAS: 13292-87-0 | C2H9BS | 75.96 g/mol

Borane-dimethyl sulfide complex is used for hydroborations and reductions. Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

  • Packaged under Argon

Chemical Identifiers

CAS 13292-87-0
Molecular Formula C2H9BS
Molecular Weight (g/mol) 75.96
MDL Number MFCD00013189
InChI Key RMHDLBZYPISZOI-UHFFFAOYSA-N
Synonym dimethyl sulfide borane, borane-methyl sulfide complex, borane dimethyl sulfide complex, borane-dimethyl sulfide, dimethyl sulfideborane, dimethyl sulfide trihydroboron, borane-dimethyl sulfide complex, borane methylsulfide, borane dimethylsulfide, borane dms
PubChem CID 9833925
IUPAC Name boron;methylsulfanylmethane
SMILES B.CSC

Specifications

Color Colorless
Density 0.856 g/mL
Flash Point 7°C (45°F)
Packaging ChemSeal™ bottles
Linear Formula (CH3)2S·BH3
Quantity 100 mL
UN Number UN3399
Beilstein 3663489
Sensitivity Air and moisture sensitive
Solubility Information It reacts with water. Miscible with diethyl ether,methylene chloride,hexane,heptane,petroleum ether,tetrahydrofuran,diglyme,benzene,toluene and xylene.
Formula Weight 75.97
Concentration or Composition (by Analyte or Components) 2M in toluene
Physical Form Liquid
Chemical Name or Material Borane-dimethyl sulfide complex
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Safety and Handling

Hazard Category H225-H260-H302-H304-H315-H318-H335-H336-H361d-H373
Hazard Statement GHS H Statement
H225-H260-H300-H304-H361-H373-H314-H336
Highly flammable liquid and vapor.
In contact with water releases flammable gases which may ignite spontaneously.
Fatal if swallowed.
May be fatal if swallowed and enters airways.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Causes severe skin burns and eye damage.
May cause drowsiness or dizziness.
Precautionary Statement P201-P202-P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P281-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P308+P313-P310-P330-P331-P332+P313-P335
DOTInformation Transport Hazard Class: 4.3; Packing Group: I; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE
TSCA Yes
storageNote1
  • Packaged under Argon
Recommended Storage Ambient temperatures; Store under Argon

RUO – Research Use Only