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Bismuth(III) trifluoromethanesulfonate, 99%
CAS: 88189-03-1 | C3BiF9O9S3 | 656.17 g/mol
$133.81 - $466.04
Chemical Identifiers
| CAS | 88189-03-1 |
|---|---|
| Molecular Formula | C3BiF9O9S3 |
| Molecular Weight (g/mol) | 656.17 |
| MDL Number | MFCD02093669 |
| InChI Key | NYENCOMLZDQKNH-UHFFFAOYSA-K |
| Synonym | bismuth iii trifluoromethanesulfonate, bismuth triflate, bismuth trifluoromethanesulfonate, bismuth 3+ triflate, bismuth triflate mi, bismuth 3+ trifluoromethanesulfonate, bismuth tris trifluoromethanesulfonate, bismuth iii triflate, bismuth 3+ ion tritriflate |
| PubChem CID | 9917655 |
| IUPAC Name | bismuth;trifluoromethanesulfonate |
| SMILES | C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Bi+3] |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
|---|---|---|---|---|---|---|---|---|---|
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAL1968706
|
Thermo Scientific Chemicals
L1968706 |
5 g |
Each for $133.81
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AAL1968714
|
Thermo Scientific Chemicals
L1968714 |
25 g |
Each for $466.04
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Description
Bismuth(III) trifluoromethanesulfonate acts as a catalyst in Friedel-Crafts acylation and cycloisomerization of allene-enol ethers. It behaves as a direct substitution catalyst and involved in the substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carboxamides and carbamates. Further, it is also used in Mukaiyama aldol reactions.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsBismuth(III) trifluoromethanesulfonate acts as a catalyst in Friedel-Crafts acylation and cycloisomerization of allene-enol ethers. It behaves as a direct substitution catalyst and involved in the substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carboxamides and carbamates. Further, it is also used in Mukaiyama aldol reactions.
Solubility
Soluble in organics acetonitrile, dioxane, dimethyl formamide and dimethyl sulfoxide.
Notes
Hygroscopic. Incompatible with strong oxidizing agents.
Chemical Identifiers
| 88189-03-1 | |
| 656.17 | |
| NYENCOMLZDQKNH-UHFFFAOYSA-K | |
| 9917655 | |
| C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Bi+3] |
| C3BiF9O9S3 | |
| MFCD02093669 | |
| bismuth iii trifluoromethanesulfonate, bismuth triflate, bismuth trifluoromethanesulfonate, bismuth 3+ triflate, bismuth triflate mi, bismuth 3+ trifluoromethanesulfonate, bismuth tris trifluoromethanesulfonate, bismuth iii triflate, bismuth 3+ ion tritriflate | |
| bismuth;trifluoromethanesulfonate |
Specifications
| 88189-03-1 | |
| C3BiF9O9S3 | |
| MFCD02093669 | |
| UN3261 | |
| bismuth iii trifluoromethanesulfonate, bismuth triflate, bismuth trifluoromethanesulfonate, bismuth 3+ triflate, bismuth triflate mi, bismuth 3+ trifluoromethanesulfonate, bismuth tris trifluoromethanesulfonate, bismuth iii triflate, bismuth 3+ ion tritriflate | |
| NYENCOMLZDQKNH-UHFFFAOYSA-K | |
| bismuth;trifluoromethanesulfonate | |
| 9917655 | |
| 99% |
| >300°C | |
| (CF3SO3)3Bi | |
| 5 g | |
| Hygroscopic | |
| Soluble in organics acetonitrile,dioxane,dimethyl formamide and dimethyl sulfoxide. | |
| C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Bi+3] | |
| 656.17 | |
| 656.19 | |
| Bismuth(III) trifluoromethanesulfonate |
Safety and Handling
GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.
P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
H314
DOTInformation : Transport Hazard Class: 8; Packing Group: III; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only