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Allyltri-n-butyltin, 97%

Catalog No. p-7046365
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AAL1408706 5 g
AAL1408714 25 g
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Catalog No. AAL1408706 Supplier Thermo Scientific Chemicals Supplier No. L1408706
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This chemical may require us to obtain additional information for our regulatory and chemical compliance records. If required, we will contact you for this information once your order is placed.

Description

CAS: 24850-33-7 | C15H32Sn | 331.13 g/mol

Allyltri-n-butyltin acts as an allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate. It is also used to prepare homoallylic alcohols with trichloro-1,3,5-triazene. Further, it plays an important role for tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reaction with iodoquinones and allyl acetates.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Allyltri-n-butyltin acts as an allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate. It is also used to prepare homoallylic alcohols with trichloro-1,3,5-triazene. Further, it plays an important role for tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reaction with iodoquinones and allyl acetates.

Solubility
Immiscible with water.

Notes
Air sensitive. Incompatible with strong oxidizing agents.

Chemical Identifiers

CAS 24850-33-7
Molecular Formula C15H32Sn
Molecular Weight (g/mol) 331.13
MDL Number MFCD00010346
InChI Key YLGRTLMDMVAFNI-UHFFFAOYSA-N
Synonym allyltributyltin, allyltributylstannane, allyltri-n-butyltin, stannane, tributyl-2-propenyl, tributyl prop-2-en-1-yl stannane, allyl tributyl stannane, unii-aor8od4103, tributyl-2-propenylstannane, tri-n-butyl-2-propenylstannane, allyl tributyltin
PubChem CID 90628
SMILES CCCC[Sn](CCCC)(CCCC)CC=C

Specifications

Density 1.079
Boiling Point 100°C to 102°C (0.5 mmHg)
Flash Point 103°C (217°F)
Refractive Index 1.486
Quantity 5 g
UN Number UN2788
Beilstein 3588340
Sensitivity Air sensitive
Solubility Information Immiscible with water.
IUPAC Name tributyl(prop-2-enyl)stannane
Formula Weight 331.12
Percent Purity 97%
Chemical Name or Material Allyltri-n-butyltin
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Safety and Handling

Hazard Category H301-H312-H315-H319-H372
Hazard Statement GHS H Statement
H301-H372-H312-H315-H319
Toxic if swallowed.
Causes damage to organs through prolonged or repeated exposure.
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye irritation.
Precautionary Statement P260-P264b-P270-P280-P301+P310-P302+P352-P305+P351+P338-P312-P314-P330-P332+P313-P362-P501c
DOTInformation Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: ORGANOTIN COMPOUNDS, LIQUID, N.O.S.
EINECSNumber 246-494-3
TSCA No
Recommended Storage Keep cold; Store under Argon

RUO – Research Use Only