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Allylmagnesium chloride, 1M in MeTHF

Catalog No. p-7033967
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AAH51170AE 100 mL
AAH51170AP 500 mL
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Catalog No. AAH51170AE Supplier Thermo Scientific Chemicals Supplier No. H51170AE
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Description

CAS: 2622-05-1 | C3H5ClMg | 100.83 g/mol

Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5?-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.

Solubility
It reacts violently with water.

Notes
Air & moisture sensitive. Stable under recommended storage conditions.

Chemical Identifiers

CAS 2622-05-1
Molecular Formula C3H5ClMg
Molecular Weight (g/mol) 100.83
MDL Number MFCD00000473
InChI Key PLYLAFITHJUEGX-UHFFFAOYSA-M
Synonym allylmagnesium chloride, magnesium, chloro-2-propenyl, magnesium, chloro-2-propen-1-yl, chloro prop-2-en-1-yl magnesium, allylmagnesium chloride solution, 2.0 m in thf, sjpdadpprujp@, allylmagnesiumchloride, allyl magnesium chloride, allyl-magnesium chloride, 2-propenyl magnesium chloride
PubChem CID 75804
IUPAC Name magnesium;prop-1-ene;chloride
SMILES Cl[Mg]CC=C

Specifications

Linear Formula CH2=CHCH2MgCl
Quantity 100 mL
UN Number UN3399
Sensitivity Air and moisture sensitive
Solubility Information It reacts violently with water.
Formula Weight 100.83
Concentration or Composition (by Analyte or Components) 1M in MeTHF
Chemical Name or Material Allylmagnesium chloride

Safety and Handling

Hazard Category H225-H260-H302-H314-H335
Hazard Statement GHS H Statement
H225-H261-H314-H318
Highly flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Causes serious eye damage.
Precautionary Statement P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P335+P334-P363-P370+P378q-P501c
DOTInformation Transport Hazard Class: 4.3; Packing Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE
TSCA Yes
Recommended Storage Ambient temperatures

RUO – Research Use Only