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4-(Methoxycarbonyl)benzeneboronic acid, 97%
CAS: 99768-12-4 | C8H9BO4 | 179.966 g/mol
$126.38 - $370.71
Chemical Identifiers
| CAS | 99768-12-4 |
|---|---|
| Molecular Formula | C8H9BO4 |
| Molecular Weight (g/mol) | 179.966 |
| MDL Number | MFCD01632203 |
| InChI Key | PQCXFUXRTRESBD-UHFFFAOYSA-N |
| Synonym | methyl 4-boronobenzoate, 4-methoxycarbonyl phenylboronic acid, 4-methoxycarbonyl phenyl boronic acid, 4-methoxycarbonyl benzeneboronic acid, 4-methoxycarbonylphenyl boronic acid, methyl4-boronobenzoate, 4-methoxycarbonylbenzeneboronic acid, p-methoxycarbonyl phenylboronic acid, 4-methoxycabonyl phenylboronic acid |
| PubChem CID | 2734369 |
| IUPAC Name | (4-methoxycarbonylphenyl)boronic acid |
| SMILES | B(C1=CC=C(C=C1)C(=O)OC)(O)O |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAH2762703
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Thermo Scientific Chemicals
H2762703 |
1 g |
Each for $126.38
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AAH2762706
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Thermo Scientific Chemicals
H2762706 |
5 g |
Each for $370.71
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Description
It is a reagent used for tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence, copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, one-pot ipso-nitration of arylboronic acids, copper-catalyzed nitration and cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling. It is employed as reagent in Reagent used in preparation of biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid, chromenones and their bradykinin B1 antagonistic activity, Pt nanoparticles on Photoactive metal-organic frameworks resulting in efficient hydrogen evolution via synergistic photoexcitation and electron injection and salicylate-based thienylbenzoic acids as E. coli methionine aminopeptidase inhibitor.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsIt is a reagent used for tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence, copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, one-pot ipso-nitration of arylboronic acids, copper-catalyzed nitration and cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling. It is employed as reagent in Reagent used in preparation of biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid, chromenones and their bradykinin B1 antagonistic activity, Pt nanoparticles on Photoactive metal-organic frameworks resulting in efficient hydrogen evolution via synergistic photoexcitation and electron injection and salicylate-based thienylbenzoic acids as E. coli methionine aminopeptidase inhibitor.
Solubility
Soluble in methanol.
Notes
Store in cool dry conditions. Incompatible with oxidizing agents. Ensure good ventilation.
Chemical Identifiers
| 99768-12-4 | |
| 179.966 | |
| PQCXFUXRTRESBD-UHFFFAOYSA-N | |
| 2734369 | |
| B(C1=CC=C(C=C1)C(=O)OC)(O)O |
| C8H9BO4 | |
| MFCD01632203 | |
| methyl 4-boronobenzoate, 4-methoxycarbonyl phenylboronic acid, 4-methoxycarbonyl phenyl boronic acid, 4-methoxycarbonyl benzeneboronic acid, 4-methoxycarbonylphenyl boronic acid, methyl4-boronobenzoate, 4-methoxycarbonylbenzeneboronic acid, p-methoxycarbonyl phenylboronic acid, 4-methoxycabonyl phenylboronic acid | |
| (4-methoxycarbonylphenyl)boronic acid |
Specifications
| 99768-12-4 | |
| C8H9BO4 | |
| 1 g | |
| Soluble in methanol. | |
| B(C1=CC=C(C=C1)C(=O)OC)(O)O | |
| 179.966 | |
| 179.97 | |
| 4-(Methoxycarbonyl)benzeneboronic acid |
| 220°C to 225°C | |
| MFCD01632203 | |
| methyl 4-boronobenzoate, 4-methoxycarbonyl phenylboronic acid, 4-methoxycarbonyl phenyl boronic acid, 4-methoxycarbonyl benzeneboronic acid, 4-methoxycarbonylphenyl boronic acid, methyl4-boronobenzoate, 4-methoxycarbonylbenzeneboronic acid, p-methoxycarbonyl phenylboronic acid, 4-methoxycabonyl phenylboronic acid | |
| PQCXFUXRTRESBD-UHFFFAOYSA-N | |
| (4-methoxycarbonylphenyl)boronic acid | |
| 2734369 | |
| 97% |
Safety and Handling
GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
H315-H319-H335
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only