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3-Aminocrotononitrile, (E)+(Z), 96%
CAS: 1118-61-2 | C4H6N2 | 82.11 g/mol
Supplier: Thermo Scientific Chemicals L0531622
Description
3-Aminocrotononitrile reacts with ferrocenyl-1,2-enones to form ferrocenyl pyridines. It undergoes diazotization coupling reaction with p-substituted anilines to give 2-arylhydrazone-3-ketimino-butyronitriles.3-Aminocrotononitrile, (E)+(Z), is used in reaction with aryldiazonium salts gave, instead of the expected triazene, 2-arylhydrazono-3-ketobutyronitrile by electrophilic attack at the ?-carbon and hydrolysis of the resulting imine. It is also used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. 3-Aminocrotononitrile was used as bisnucleophilic reagent which on cyclocondensation with hexafluoroacetone(ethoxycarbonylimine) forms bis(trifluoromethyl)pyrimidinones.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications3-Aminocrotononitrile reacts with ferrocenyl-1,2-enones to form ferrocenyl pyridines. It undergoes diazotization coupling reaction with p-substituted anilines to give 2-arylhydrazone-3-ketimino-butyronitriles.3-Aminocrotononitrile, (E)+(Z), is used in reaction with aryldiazonium salts gave, instead of the expected triazene, 2-arylhydrazono-3-ketobutyronitrile by electrophilic attack at the É-carbon and hydrolysis of the resulting imine. It is also used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. 3-Aminocrotononitrile was used as bisnucleophilic reagent which on cyclocondensation with hexafluoroacetone(ethoxycarbonylimine) forms bis(trifluoromethyl)pyrimidinones.
Solubility
Very soluble in water, soluble in ethanol.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents.
Spécifications
| 3-Aminocrotononitrile | |
| 1118-61-2 | |
| 120°C (4 mmHg) | |
| C4H6N2 | |
| 100 g | |
| 3-aminocrotononitrile, 2z-3-aminobut-2-enenitrile, 3-amino-2-butenenitrile, z-3-aminobut-2-enenitrile, beta-aminocrotononitrile, 3-amino-2-butenonitrile, 2-amino-1-propenecarbonitrile, 3-amino-crotononitrile, beta-amino-crotononitrile, 2z-3-amino-2-butenenitrile | |
| DELJOESCKJGFML-DUXPYHPUSA-N | |
| (Z)-3-aminobut-2-enenitrile | |
| 5325263 | |
| 96% |
| (E)+(Z) | |
| ∼70°C to 75°C | |
| 154°C (309°F) | |
| MFCD00008071,MFCD00008071 | |
| 1719815 | |
| Very soluble in water,soluble in ethanol. | |
| C\C(N)=C/C#N | |
| 82.11 | |
| 82.11 |
Identifiants chimiques
| 1118-61-2 | |
| 82.11 | |
| DELJOESCKJGFML-DUXPYHPUSA-N | |
| 5325263 | |
| C\C(N)=C/C#N |
| C4H6N2 | |
| MFCD00008071,MFCD00008071 | |
| 3-aminocrotononitrile, 2z-3-aminobut-2-enenitrile, 3-amino-2-butenenitrile, z-3-aminobut-2-enenitrile, beta-aminocrotononitrile, 3-amino-2-butenonitrile, 2-amino-1-propenecarbonitrile, 3-amino-crotononitrile, beta-amino-crotononitrile, 2z-3-amino-2-butenenitrile | |
| (Z)-3-aminobut-2-enenitrile |
Sécurité et manipulation
P261-P264b-P270-P271-P272-P280g-P301+P312-P302+P352-P304+P340-P312-P330-P333+P313-P363-P501c
H302+H332-H317
missing translation for 'dotInformation' : Hazard Class: 6.1; Packaging Group: III
missing translation for 'einecsNumber' : 214-266-2
missing translation for 'tsca' : Yes
Recommended Storage : Keep cold
RUO – Research Use Only