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2-Bromoisobutyryl bromide, 97%, Thermo Scientific Chemicals
$64.66 - $357.93
Chemical Identifiers
| CAS | 20769-85-1 |
|---|---|
| Molecular Formula | C4H6Br2O |
| Molecular Weight (g/mol) | 229.899 |
| MDL Number | MFCD00000122 |
| InChI Key | YOCIJWAHRAJQFT-UHFFFAOYSA-N |
| Synonym | 2-bromo-2-methylpropionyl bromide, 2-bromoisobutyryl bromide, propanoyl bromide, 2-bromo-2-methyl, bibb, 2-bromo-2-methylpropionylbromide, unii-627f9n9dya, 2-bromoisobutyrylbromide, 2-bromo-2-methyl-propionyl bromide, alpha-bromoisobutyryl bromide, 2-bromo-2-methyl-propanoyl bromide |
| PubChem CID | 88685 |
| IUPAC Name | 2-bromo-2-methylpropanoyl bromide |
| SMILES | CC(C)(C(=O)Br)Br |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
|---|---|---|---|---|---|---|---|---|---|
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAB2424914
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Thermo Scientific Chemicals
B2424914 |
25 g |
Each for $64.66
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AAB2424922
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Thermo Scientific Chemicals
B2424922 |
100 g |
Each for $108.84
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AAB2424936
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Thermo Scientific Chemicals
B2424936 |
500 g |
Each for $357.93
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Description
2-Bromoisobutyryl bromide is used to prepare N-protected halodienamide, which provides four- and five-membered lactams in the presence of copper(I) and a tertiary amine. Further, it is used as atom transfer radical polymerization(ATRP) initiator for functionalization of hydroxyl groups present on the surface of graphene oxide. It is also used in preparation of polycaprolactone macroinitiators through reaction with oligomeric caprolactone diol and mesoporous silica nanoparticles with ATRP initiator anchored on the exterior surface.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications2-Bromoisobutyryl bromide is used to prepare N-protected halodienamide, which provides four- and five-membered lactams in the presence of copper(I) and a tertiary amine. Further, it is used as atom transfer radical polymerization(ATRP) initiator for functionalization of hydroxyl groups present on the surface of graphene oxide. It is also used in preparation of polycaprolactone macroinitiators through reaction with oligomeric caprolactone diol and mesoporous silica nanoparticles with ATRP initiator anchored on the exterior surface.
Solubility
Miscible with acetone and carbon disulfide.
Notes
Moisture sensitive. Incompatible with strong oxidizing agents and strong alkalis.
Chemical Identifiers
| 20769-85-1 | |
| 229.899 | |
| YOCIJWAHRAJQFT-UHFFFAOYSA-N | |
| 88685 | |
| CC(C)(C(=O)Br)Br |
| C4H6Br2O | |
| MFCD00000122 | |
| 2-bromo-2-methylpropionyl bromide, 2-bromoisobutyryl bromide, propanoyl bromide, 2-bromo-2-methyl, bibb, 2-bromo-2-methylpropionylbromide, unii-627f9n9dya, 2-bromoisobutyrylbromide, 2-bromo-2-methyl-propionyl bromide, alpha-bromoisobutyryl bromide, 2-bromo-2-methyl-propanoyl bromide | |
| 2-bromo-2-methylpropanoyl bromide |
Specifications
| 20769-85-1 | |
| 160°C to 162°C | |
| Acrid | |
| 1.5095 | |
| 25 g | |
| 1746128 | |
| 2-bromo-2-methylpropionyl bromide, 2-bromoisobutyryl bromide, propanoyl bromide, 2-bromo-2-methyl, bibb, 2-bromo-2-methylpropionylbromide, unii-627f9n9dya, 2-bromoisobutyrylbromide, 2-bromo-2-methyl-propionyl bromide, alpha-bromoisobutyryl bromide, 2-bromo-2-methyl-propanoyl bromide | |
| YOCIJWAHRAJQFT-UHFFFAOYSA-N | |
| 2-bromo-2-methylpropanoyl bromide | |
| 88685 | |
| 97% |
| 1.86 | |
| >110°C (230°F) | |
| C4H6Br2O | |
| MFCD00000122 | |
| UN3265 | |
| Moisture sensitive | |
| Miscible with acetone and carbon disulfide. | |
| CC(C)(C(=O)Br)Br | |
| 229.899 | |
| 229.91 | |
| 2-Bromoisobutyryl bromide |
Safety and Handling
GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.
P201-P202-P260-P264b-P270-P271-P272-P280g-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P333+P313-P363-P501c
H302-H314-H317-H335-H340
DOTInformation : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
EINECSNumber : 244-017-3
TSCA : Yes
Recommended Storage : Ambient temperatures
RUO – Research Use Only