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  7. 2-Bromoisobutyryl bromide, 97%

2-Bromoisobutyryl bromide, 97%

Catalog No. AAB2424914
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Catalog No. Quantity
AAB2424914 25 g
AAB2424922 100 g
AAB2424936 500 g
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Catalog No. AAB2424914

Supplier: Thermo Scientific Chemicals B2424914

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Description

CAS: 20769-85-1 | C4H6Br2O | 229.899 g/mol

2-Bromoisobutyryl bromide is used to prepare N-protected halodienamide, which provides four- and five-membered lactams in the presence of copper(I) and a tertiary amine. Further, it is used as atom transfer radical polymerization(ATRP) initiator for functionalization of hydroxyl groups present on the surface of graphene oxide. It is also used in preparation of polycaprolactone macroinitiators through reaction with oligomeric caprolactone diol and mesoporous silica nanoparticles with ATRP initiator anchored on the exterior surface.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2-Bromoisobutyryl bromide is used to prepare N-protected halodienamide, which provides four- and five-membered lactams in the presence of copper(I) and a tertiary amine. Further, it is used as atom transfer radical polymerization(ATRP) initiator for functionalization of hydroxyl groups present on the surface of graphene oxide. It is also used in preparation of polycaprolactone macroinitiators through reaction with oligomeric caprolactone diol and mesoporous silica nanoparticles with ATRP initiator anchored on the exterior surface.

Solubility
Miscible with acetone and carbon disulfide.

Notes
Moisture sensitive. Incompatible with strong oxidizing agents and strong alkalis.

Chemical Identifiers

CAS 20769-85-1
Molecular Formula C4H6Br2O
Molecular Weight (g/mol) 229.899
MDL Number MFCD00000122
InChI Key YOCIJWAHRAJQFT-UHFFFAOYSA-N
Synonym 2-bromo-2-methylpropionyl bromide, 2-bromoisobutyryl bromide, propanoyl bromide, 2-bromo-2-methyl, bibb, 2-bromo-2-methylpropionylbromide, unii-627f9n9dya, 2-bromoisobutyrylbromide, 2-bromo-2-methyl-propionyl bromide, alpha-bromoisobutyryl bromide, 2-bromo-2-methyl-propanoyl bromide
PubChem CID 88685
IUPAC Name 2-bromo-2-methylpropanoyl bromide
SMILES CC(C)(C(=O)Br)Br

Specifications

Density 1.86
Boiling Point 160°C to 162°C
Flash Point >110°C (230°F)
Odor Acrid
Refractive Index 1.5095
Quantity 25 g
UN Number UN3265
Beilstein 1746128
Sensitivity Moisture sensitive
Solubility Information Miscible with acetone and carbon disulfide.
Formula Weight 229.91
Percent Purity 97%
Chemical Name or Material 2-Bromoisobutyryl bromide
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Safety and Handling

Hazard Category H302-H314-H317-H335-H340
Hazard Statement GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.
Precautionary Statement P201-P202-P260-P264b-P270-P271-P272-P280g-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P333+P313-P363-P501c
DOTInformation Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
EINECSNumber 244-017-3
TSCA Yes
Recommended Storage Ambient temperatures

RUO – Research Use Only