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  7. 2,6-Di-tert-butyl-4-methylpyridine, 97%

2,6-Di-tert-butyl-4-methylpyridine, 97%

Catalog No. p-7046382
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5 g
Catalog No. Quantity
AAL1414303 1 g
AAL1414306 5 g
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Catalog No. AAL1414303

Supplier: Thermo Scientific Chemicals L1414303

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Description

CAS: 38222-83-2 | C14H23N | 205.35 g/mol

2,6-Di-tert-butyl-4-methylpyridine is used for the generation of enol triflates from ketones using trifluoromethanesulfonic anhydride. It is also used in the synthesis of 1,2-dihydro-2-silanaphthalene derivatives, as base in PtCl4-catalyzed cyclization reactions of homopropargyl azide derivatives and in diastereoselective synthesis of β-thiomannopyranosides.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2,6-Di-tert-butyl-4-methylpyridine is used for the generation of enol triflates from ketones using trifluoromethanesulfonic anhydride. It is also used in the synthesis of 1,2-dihydro-2-silanaphthalene derivatives, as base in PtCl4-catalyzed cyclization reactions of homopropargyl azide derivatives and in diastereoselective synthesis of β-thiomannopyranosides.

Solubility
Sparingly soluble in water. Soluble in ethanol, acetic acid and diethyl ether.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature is 2 - 8°C. Store under inert gas. It is sensitive to air and light.

Chemical Identifiers

CAS 38222-83-2
Molecular Formula C14H23N
Molecular Weight (g/mol) 205.35
MDL Number MFCD00006305
InChI Key HVHZEKKZMFRULH-UHFFFAOYSA-N
Synonym 2,6-di-tert-butyl-4-methylpyridine, dtbmp, pyridine, 2,6-bis 1,1-dimethylethyl-4-methyl, 2,6-di-t-butyl-4-methylpyridine, 2,6-ditert-butyl-4-methyl-pyridine, 2,6-bis tert-butyl-4-methylpyridine, pubchem10244, acmc-209iyr, ksc490s2n, 2,6-di-t-butyl 4-methylpyridine
PubChem CID 98898
SMILES CC1=CC(=NC(=C1)C(C)(C)C)C(C)(C)C

Specifications

Melting Point 30°C to 35°C
Boiling Point 232°C to 234°C
Flash Point 83°C (181°F)
Refractive Index 1.4765
Quantity 1 g
Beilstein 130503
Sensitivity Air and light sensitive
Solubility Information Sparingly soluble in water. Soluble in ethanol,acetic acid and diethyl ether.
IUPAC Name 2,6-ditert-butyl-4-methylpyridine
Formula Weight 205.35
Percent Purity 97%
Chemical Name or Material 2,6-Di-tert-butyl-4-methylpyridine
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Safety and Handling

Hazard Category H228-H315-H319-H335
Hazard Statement GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c
DOTInformation Hazard Class: 4.1; Packaging Group: II
EINECSNumber 253-834-4
TSCA No
Recommended Storage Keep cold; Store under Nitrogen

RUO – Research Use Only