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1-Methylpiperidine, 99%

Catalog No. aal0339836
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Catalog No. Quantity
AAL0339836 500 g
AAL0339809 10 g
AAL0339822 100 g
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Catalog No. AAL0339836

Supplier: Thermo Scientific Chemicals L0339836

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Description

CAS: 626-67-5 | C6H14ClN | 135.64 g/mol

1-Methylpiperidine is a reactant for sp3 C-H Bond activation with ruthenium(II) catalysts and C(3)-alkylation of cyclic amines, One-pot synthesis of Z-cinnamic acids. It is used in the synthesis of Unsymmetrical ureas, Antibacterial imidazolium, pyrrolidinium, and piperidinium salts, C1-C16 segment of goniodomin A via palladium-catalyzed organostannane thioester coupling.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-Methylpiperidine is a reactant for sp3 C-H Bond activation with ruthenium(II) catalysts and C(3)-alkylation of cyclic amines, One-pot synthesis of Z-cinnamic acids. It is used in the synthesis of Unsymmetrical ureas, Antibacterial imidazolium, pyrrolidinium, and piperidinium salts, C1-C16 segment of goniodomin A via palladium-catalyzed organostannane thioester coupling.

Solubility
Fully miscible in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with.acids, Acid chlorides, Acid anhydrides, Strong oxidizing agents, Carbon dioxide.

Chemical Identifiers

CAS 626-67-5
Molecular Formula C6H14ClN
Molecular Weight (g/mol) 135.64
MDL Number MFCD00006491
InChI Key QDUXDCXILAPLAG-UHFFFAOYSA-N
Synonym n-methylpiperidine, piperidine, 1-methyl, methylpiperidine, n-methyl piperidine, 1-methyl-piperidine, n-methylpiperidin, methylpiperdine, 1-methylpiperadine, n-methyl-piperidine, 1-methyl piperidine
PubChem CID 12291
IUPAC Name 1-methylpiperidine
SMILES [H+].[Cl-].CN1CCCCC1

Specifications

Melting Point -50°C
Density 0.816
pH 12
Boiling Point 105°C to 107°C
Flash Point 3°C (37°F)
Odor Amine-like
Refractive Index 1.4378
Quantity 500 g
UN Number UN2399
Beilstein 1073
Solubility Information Fully miscible in water.
Formula Weight 99.18
Percent Purity 99%
Chemical Name or Material 1-Methylpiperidine
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Safety and Handling

Hazard Category H225-H302+H312+H332-H314-H335
Hazard Statement GHS H Statement
H225-H331-H314-H318-H302
Highly flammable liquid and vapor.
Toxic if inhaled.
Causes severe skin burns and eye damage.
Causes serious eye damage.
Harmful if swallowed.
Precautionary Statement P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c
DOTInformation Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: 1-METHYLPIPERIDINE
EINECSNumber 210-959-9
RTECSNumber TN1225000
TSCA Yes
Recommended Storage Ambient temperatures

RUO – Research Use Only