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1-Iodo-2-(trimethylsilyl)acetylene, 97%
CAS: 18163-47-8 | C5H9ISi | 224.12 g/mol
$77.51 - $863.23
Chemical Identifiers
| CAS | 18163-47-8 |
|---|---|
| Molecular Formula | C5H9ISi |
| Molecular Weight (g/mol) | 224.12 |
| MDL Number | MFCD00274201 |
| InChI Key | HNIRHTRSZDSMOF-UHFFFAOYSA-N |
| Synonym | 1-iodo-2-trimethylsilyl acetylene, iodoethynyl trimethylsilane, silane, iodomethyl trimethyl, 2-iodoethynyl trimethylsilane, 2-iodoethynyl trimethyl silane, silane, iodoethynyl trimethyl, tbdmcs, acmc-20aoug, trimethyliodoethinylsilane, iodoethynyltrimethylsilane |
| PubChem CID | 140341 |
| IUPAC Name | 2-iodoethynyl(trimethyl)silane |
| SMILES | C[Si](C)(C)C#CI |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAH5337503
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Thermo Scientific Chemicals
H5337503 |
1 g |
Each for $77.51
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AAH5337506
|
Thermo Scientific Chemicals
H5337506 |
5 g |
Each for $250.67
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AAH5337514
|
Thermo Scientific Chemicals
H5337514 |
25 g |
Each for $863.23
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Description
1-Iodo-2-(trimethylsilyl)acetylene may be used to investigate the reactivity of diamagnetic cobalt(I) complex, Tol-BDI((2-pp)2)Co [Tol-BDI((2-pp)2)H = 2-(4-tolyl)-1,3-bis(2-isopropylpyridyl)propenediimine]. It may be used for the synthesis of 1-(4-trimethylsilanylbuta-1,3-diynyl)pyrene, via Pd-coupling with 1-iodo-2-trimethylsilylacetylene.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications1-Iodo-2-(trimethylsilyl)acetylene may be used to investigate the reactivity of diamagnetic cobalt(I) complex, Tol-BDI((2-pp)2)Co [Tol-BDI((2-pp)2)H = 2-(4-tolyl)-1,3-bis(2-isopropylpyridyl)propenediimine]. It may be used for the synthesis of 1-(4-trimethylsilanylbuta-1,3-diynyl)pyrene, via Pd-coupling with 1-iodo-2-trimethylsilylacetylene.
Notes
Light sensitive. Incompatible with oxidizing agents.
Chemical Identifiers
| 18163-47-8 | |
| 224.12 | |
| HNIRHTRSZDSMOF-UHFFFAOYSA-N | |
| 140341 | |
| C[Si](C)(C)C#CI |
| C5H9ISi | |
| MFCD00274201 | |
| 1-iodo-2-trimethylsilyl acetylene, iodoethynyl trimethylsilane, silane, iodomethyl trimethyl, 2-iodoethynyl trimethylsilane, 2-iodoethynyl trimethyl silane, silane, iodoethynyl trimethyl, tbdmcs, acmc-20aoug, trimethyliodoethinylsilane, iodoethynyltrimethylsilane | |
| 2-iodoethynyl(trimethyl)silane |
Specifications
| 130°C | |
| 1 g | |
| (CH3)3SiC≡CI | |
| UN1993 | |
| 1-iodo-2-trimethylsilyl acetylene, iodoethynyl trimethylsilane, silane, iodomethyl trimethyl, 2-iodoethynyl trimethylsilane, 2-iodoethynyl trimethyl silane, silane, iodoethynyl trimethyl, tbdmcs, acmc-20aoug, trimethyliodoethinylsilane, iodoethynyltrimethylsilane | |
| C[Si](C)(C)C#CI | |
| 224.12 | |
| 224.12 | |
| 1.511 | |
| 1.46 |
| 18163-47-8 | |
| C5H9ISi | |
| MFCD00274201 | |
| 48°C (118°F) | |
| HNIRHTRSZDSMOF-UHFFFAOYSA-N | |
| 2-iodoethynyl(trimethyl)silane | |
| 140341 | |
| 97% | |
| Light sensitive | |
| 1-Iodo-2-(trimethylsilyl)acetylene |
Safety and Handling
GHS H Statement
H301-H311-H334-H361-H226-H332-H317
Toxic if swallowed.
Toxic in contact with skin.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Suspected of damaging fertility or the unborn child.
Flammable liquid and vapor.
Harmful if inhaled.
May cause an allergic skin reaction.
P201-P202-P210-P233-P240-P241-P242-P243-P261-P264b-P270-P271-P272-P280g-P281-P285-P301+P312-P303+P361+P353-P304+P340-P308+P313-P312-P330-P333+P313-P342+P311-P363-P370+P378q-P5
H226-H302+H312+H332-H317-H334-H361
DOTInformation : Transport Hazard Class: 3; Packing Group: III; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only