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  7. 1-Iodo-2-(trimethylsilyl)acetylene, 97%

1-Iodo-2-(trimethylsilyl)acetylene, 97%

Catalog No. aah5337503
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Catalog No. Quantity
AAH5337503 1 g
AAH5337506 5 g
AAH5337514 25 g
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Catalog No. AAH5337503

Supplier: Thermo Scientific Chemicals H5337503

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Description

CAS: 18163-47-8 | C5H9ISi | 224.12 g/mol

1-Iodo-2-(trimethylsilyl)acetylene may be used to investigate the reactivity of diamagnetic cobalt(I) complex, Tol-BDI((2-pp)2)Co [Tol-BDI((2-pp)2)H = 2-(4-tolyl)-1,3-bis(2-isopropylpyridyl)propenediimine]. It may be used for the synthesis of 1-(4-trimethylsilanylbuta-1,3-diynyl)pyrene, via Pd-coupling with 1-iodo-2-trimethylsilylacetylene.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-Iodo-2-(trimethylsilyl)acetylene may be used to investigate the reactivity of diamagnetic cobalt(I) complex, Tol-BDI((2-pp)2)Co [Tol-BDI((2-pp)2)H = 2-(4-tolyl)-1,3-bis(2-isopropylpyridyl)propenediimine]. It may be used for the synthesis of 1-(4-trimethylsilanylbuta-1,3-diynyl)pyrene, via Pd-coupling with 1-iodo-2-trimethylsilylacetylene.

Notes
Light sensitive. Incompatible with oxidizing agents.

Chemical Identifiers

CAS 18163-47-8
Molecular Formula C5H9ISi
Molecular Weight (g/mol) 224.12
MDL Number MFCD00274201
InChI Key HNIRHTRSZDSMOF-UHFFFAOYSA-N
Synonym 1-iodo-2-trimethylsilyl acetylene, iodoethynyl trimethylsilane, silane, iodomethyl trimethyl, 2-iodoethynyl trimethylsilane, 2-iodoethynyl trimethyl silane, silane, iodoethynyl trimethyl, tbdmcs, acmc-20aoug, trimethyliodoethinylsilane, iodoethynyltrimethylsilane
PubChem CID 140341
IUPAC Name 2-iodoethynyl(trimethyl)silane
SMILES C[Si](C)(C)C#CI

Specifications

Boiling Point 130°C
Quantity 1 g
Linear Formula (CH3)3SiC≡CI
UN Number UN1993
Flash Point 48°C (118°F)
Formula Weight 224.12
Percent Purity 97%
Refractive Index 1.511
Sensitivity Light sensitive
Density 1.46
Chemical Name or Material 1-Iodo-2-(trimethylsilyl)acetylene
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Safety and Handling

Hazard Category H226-H302+H312+H332-H317-H334-H361
Hazard Statement GHS H Statement
H301-H311-H334-H361-H226-H332-H317
Toxic if swallowed.
Toxic in contact with skin.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Suspected of damaging fertility or the unborn child.
Flammable liquid and vapor.
Harmful if inhaled.
May cause an allergic skin reaction.
Precautionary Statement P201-P202-P210-P233-P240-P241-P242-P243-P261-P264b-P270-P271-P272-P280g-P281-P285-P301+P312-P303+P361+P353-P304+P340-P308+P313-P312-P330-P333+P313-P342+P311-P363-P370+P378q-P5
DOTInformation Transport Hazard Class: 3; Packing Group: III; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
TSCA No
Recommended Storage Ambient temperatures

RUO – Research Use Only