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1-Formylpiperidine, 99%

Catalog No. p-7027017
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Catalog No. AAB2345218 Supplier Thermo Scientific Chemicals Supplier No. B2345218
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CAS: 2591-86-8 | C6H11NO | 113.16 g/mol

1-Formylpiperidine reacts with Grignard or alkyllithium reagents gives aldehydes in high yield. It can be used as a polar aprotic solvent, with better hydrocarbon solubility than other amide solvents such as dimethylformamide. In some formylation reaction of alkyllithium compounds it gives higher yields than the DMF.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-Formylpiperidine reacts with Grignard or alkyllithium reagents gives aldehydes in high yield. It can be used as a polar aprotic solvent, with better hydrocarbon solubility than other amide solvents such as dimethylformamide. In some formylation reaction of alkyllithium compounds it gives higher yields than the DMF.

Solubility
Freely soluble in water.

Notes
Incompatible materials are oxidizing agents. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Chemical Identifiers

CAS 2591-86-8
Molecular Formula C6H11NO
Molecular Weight (g/mol) 113.16
MDL Number MFCD00006483
InChI Key FEWLNYSYJNLUOO-UHFFFAOYSA-N
Synonym n-formylpiperidine, 1-formylpiperidine, 1-piperidinecarboxaldehyde, formylpiperidine, n-formylpiperidin, piperidinoformamide, piperidine-n-carbaldehyde, piperidine, 1-formyl, 1-piperidinecarbaldehyde, unii-ziq29h6czg
PubChem CID 17429
ChEBI CHEBI:42546
IUPAC Name piperidine-1-carbaldehyde
SMILES C1CCN(CC1)C=O

Specifications

Melting Point -31°C
Density 1.019
Boiling Point 222°C
Flash Point 102°C (215°F)
Refractive Index 1.484
Quantity 50 g
Beilstein 107697
Solubility Information Freely soluble in water.
Formula Weight 113.16
Percent Purity 99%
Chemical Name or Material 1-Formylpiperidine
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Hazard Category H227-H302-H311-H315-H319-H335
Hazard Statement GHS H Statement
H301-H311-H227-H315-H319-H335
Toxic if swallowed.
Toxic in contact with skin.
Combustible liquid.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P210-P235-P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P361-P363-P370+P378q-P501c
DOTInformation Hazard Class: 6.1; Packaging Group: III
EINECSNumber 219-986-0
RTECSNumber TN0380000
TSCA Yes
Recommended Storage Ambient temperatures

RUO – Research Use Only