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Alfa Aesar™ Zirconium(IV) chloride, 98%, cont. 1-2% hafnium(IV) chloride

Chemical Identifiers

Chemical Name or Material Zirconium(IV) chloride
CAS 10026-11-6
Molecular Formula ZrCl4
Formula Weight 233.03g/mol
MDL Number MFCD00011306
UN Number UN2503
Merck Index 14,10174
Synonym Zirconium tetrachloride
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAL1489118

 
alfa aesar™
L14891-18
50g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.

AAL1489130

 
alfa aesar™
L14891-30
250g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Description & Specifications

Specifications

Melting Point 331°C (subl.)
Quantity 50g
Chemical Name or Material Zirconium(IV) chloride
CAS 10026-11-6
Assay 98%
Assay Percent Notes cont. 1 to 2% hafnium(IV) chloride
Molecular Formula ZrCl4
Formula Weight 233.03g/mol
MDL Number MFCD00011306
UN Number UN2503
Merck Index 14,10174
Synonym Zirconium tetrachloride
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H314-H318-H302
Causes severe skin burns and eye damage.
Causes serious eye damage.
Harmful if swallowed.
Health Hazard 3 GHS P Statement
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
DOT Information Transport Hazard Class: 8; Packing Group: III; Proper Shipping Name: ZIRCONIUM TETRACHLORIDE
RTECS Number ZH7175000
TSCA TSCA

Applications
Zirconium(IV) chloride catalyzes the trans-hydrostannylation of acetylenes with Tri-n-butyl­tin hydride. It is used as a superior catalyst for the fries rearrangement of aryl acetates, giving the least hindered ortho-acetyl phenol in high yields at ambient temperatures. In the presence of ZrCl4, chloromethyl ethers are formed under mild conditions from acid chlorides and trioxane or paraformaldehyde.

Solubility
Reacts with water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Handle and store under inert gas. It is sensitive to moisture. Incompatible with bases and oxidizing agents.

Safety and Handling

Danger

GHS P Statement
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H314-H318-H302
Causes severe skin burns and eye damage.
Causes serious eye damage.
Harmful if swallowed.