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Triphenylphosphine sulfide, 98%, Thermo Scientific Chemicals

$335.82 - $335.82

Chemical Identifiers

CAS 3878-45-3
Molecular Formula C18H15PS
Molecular Weight (g/mol) 294.35
MDL Number MFCD00004917
InChI Key VYNGFCUGSYEOOZ-UHFFFAOYSA-N
Synonym triphenylphosphine sulfide, phosphine sulfide, triphenyl, triphenylphosphine sulphide, triphenylphosphine sulphide, triphenylphosphine monosulfide, triphenylphosphane sulfide, triphenylphosphino-1-thione, triphenylphosphorus sulfide, triphenylphosphorus sulfide, triphenyl-, triphenyl-
PubChem CID 19758
IUPAC Name triphenyl(sulfanylidene)-$l^{5}-phosphane
SMILES S=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
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Products 1
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AAA1688422
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Thermo Scientific Chemicals
A1688422
100 g
Each for $335.82
 
Description

Description

Triphenylphosphine sulfide involves in the , conversion of epoxides to episulfides (thiiranes) in presence of TFA of the same stereochemistry. It acts as a ligand for the Pd-catalyzed bisalkoxycarbonylation of olefins.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Triphenylphosphine sulfide involves in the , conversion of epoxides to episulfides (thiiranes) in presence of TFA of the same stereochemistry. It acts as a ligand for the Pd-catalyzed bisalkoxycarbonylation of olefins.

Solubility
Insoluble in water.

Notes
Store in a cool, dry, conditions in well sealed container. Store away from oxidizing agents.
Specifications

Chemical Identifiers

3878-45-3
294.35
VYNGFCUGSYEOOZ-UHFFFAOYSA-N
19758
S=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
C18H15PS
MFCD00004917
triphenylphosphine sulfide, phosphine sulfide, triphenyl, triphenylphosphine sulphide, triphenylphosphine sulphide, triphenylphosphine monosulfide, triphenylphosphane sulfide, triphenylphosphino-1-thione, triphenylphosphorus sulfide, triphenylphosphorus sulfide, triphenyl-, triphenyl-
triphenyl(sulfanylidene)-$l^{5}-phosphane

Specifications

3878-45-3
C18H15PS
100 g
645872
Insoluble in water.
S=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
294.35
294.36
Triphenylphosphine sulfide
158°C to 164°C
MFCD00004917
UN3464
triphenylphosphine sulfide, phosphine sulfide, triphenyl, triphenylphosphine sulphide, triphenylphosphine sulphide, triphenylphosphine monosulfide, triphenylphosphane sulfide, triphenylphosphino-1-thione, triphenylphosphorus sulfide, triphenylphosphorus sulfide, triphenyl-, triphenyl-
VYNGFCUGSYEOOZ-UHFFFAOYSA-N
triphenyl(sulfanylidene)-$l^{5}-phosphane
19758
98%
Safety and Handling

Safety and Handling

GHS H Statement
H331-H302-H312-H315-H319-H335
Toxic if inhaled.
Harmful if swallowed.
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P264b-P270-P280-P301+P312-P302+P352-P312-P330-P363-P501c

H302+H312

DOTInformation : Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: ORGANOPHOSPHORUS COMPOUND, TOXIC, SOLID, N.O.S.

EINECSNumber : 223-407-7

RTECSNumber : SZ2820000

TSCA : No

Recommended Storage : Ambient temperatures

SDS
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RUO – Research Use Only