missing translation for 'onlineSavingsMsg'
Learn More
Please login to your online account to display your discounted pricing

Alfa Aesar™ (Trimethylsilyl)diazomethane, 2M in hexanes

$89.73 - $292.46

Chemical Identifiers

CAS 18107-18-1
Molecular Formula C4H10N2Si
Formula Weight 114.22
MDL Number MFCD00053946
UN Number UN3383
Beilstein 1902903
Synonym (Diazomethyl)trimethylsilane
Chemical Name or Material (Trimethylsilyl)diazomethane
View More Specs


Products ${productFamilyLength}
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AAH26744AA SDS Alfa Aesar™
H26744AA
5mL Each for $89.73
AAH26744AC SDS Alfa Aesar™
H26744AC
25mL Each for $292.46
AAH26744AE SDS Alfa Aesar™
H26744AE
100mL N/A N/A  
Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Specifications

Description

Applications
(Trimethylsilyl)diazomethane is used as a methylating agent in organic chemistry. It is utilized in Gas Chromatography- Mass-Spectrometry (GC-MS) for the analysis of various carboxylic compounds. It is involved as a reagent in the Doyle-Kirmse reaction with allyl sulfides and allyl amines. It is considered and used as a less-explosive replacement fordiazomethane. It is also used as a reactant for Unnatural alfa-amino acid derivatives containing gem-bisphosphonates through Michael addition reaction, imidazolo[2,1-b]benzothiazole derivatives and aigialomycin D analogues.

Solubility
Immiscible with water. Miscible with organic solvents.

Notes
(Trimethylsilyl)diazomethane (TMSD) in alcoholic solvents under acidic or basic conditions can lead to the formation of diazomethane. TMSD is under review by the National Toxicological Program for potential inhalation hazards.Incompatible with oxidizing agents, chlorine, fluorine and perchlorates.
Description & Specifications

Chemical Identifiers

18107-18-1
114.22
UN3383
(Diazomethyl)trimethylsilane
C4H10N2Si
MFCD00053946
1902903
(Trimethylsilyl)diazomethane

Specifications

114.22
−23°C (−10°F)
5mL
MFCD00053946
C4H10N2Si
(Trimethylsilyl)diazomethane
1902903
UN3383
2M in hexanes
18107-18-1
(Diazomethyl)trimethylsilane

Safety and Handling

GHS H Statement
H225-H331-H350-H304-H361-H373-H315-H336
Highly flammable liquid and vapor.
Toxic if inhaled.
May cause cancer.
May be fatal if swallowed and enters airways.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Causes skin irritation.
May cause drowsiness or dizziness.

GHS P Statement
P210-P260-P301+P310-P303+P361+P353-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Do not breathe dust/fume/gas/mist/vapors/spray.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Danger

DOTInformation : Transport Hazard Class: 6.1; Packing Group: I; Proper Shipping Name: TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S.