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Alfa Aesar™ Trimethylsilyl azide, 94%

$47.18 - $393.24

Chemical Identifiers

CAS 4648-54-8
Molecular Formula C3H9N3Si
Molecular Weight (g/mol) 115.211
MDL Number MFCD00001986
InChI Key SEDZOYHHAIAQIW-UHFFFAOYSA-N
Synonym trimethylsilyl azide, silane, azidotrimethyl, trimethylsilylazide, azido trimethyl silane, ccris 8048, tms azide, tms-azide, trimethyl silylazide, trimethylsilyl-azide, azido trimethylsilane
PubChem CID 78378
IUPAC Name azido(trimethyl)silane
SMILES C[Si](C)(C)N=[N+]=[N-]
View More Specs

Products 3
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AAL0017306 View Documents Alfa Aesar™
L0017306
5g Each for $47.18
 
AAL0017314 View Documents Alfa Aesar™
L0017314*
25g Each for $132.16
 
AAL0017322 View Documents Alfa Aesar™
L0017322
100g Each for $393.24
 
Description

Description

Applications
Trimethylsilyl azide is used as an azidonation reagent for amines, amides, aldehydes and ketones. It is involved in the preparation of alfa- and beta-siloxy azides from carbonyl compounds and epoxides. It is also used in the preparation of heterocyclic compounds and also acts as an effective substitute for hydrazoic acid. Further, it is used in the Oseltamivir total synthesis.

Solubility
Miscible with toluene, dichloromethane, diethyl ether and most organic solvents.

Notes
Moisture sensitive. Store in a cool place. Incompatible with strong oxidizing agents and strong acids.
Specifications

Chemical Identifiers

4648-54-8
115.211
SEDZOYHHAIAQIW-UHFFFAOYSA-N
78378
C[Si](C)(C)N=[N+]=[N-]
C3H9N3Si
MFCD00001986
trimethylsilyl azide, silane, azidotrimethyl, trimethylsilylazide, azido trimethyl silane, ccris 8048, tms azide, tms-azide, trimethyl silylazide, trimethylsilyl-azide, azido trimethylsilane
azido(trimethyl)silane

Specifications

6°C (42°F)
-95°C
4648-54-8
MFCD00001986
1903730
SEDZOYHHAIAQIW-UHFFFAOYSA-N
azido(trimethyl)silane
78378
94%
95°C to 99°C
5g
C3H9N3Si
UN1992
trimethylsilyl azide, silane, azidotrimethyl, trimethylsilylazide, azido trimethyl silane, ccris 8048, tms azide, tms-azide, trimethyl silylazide, trimethylsilyl-azide, azido trimethylsilane
C[Si](C)(C)N=[N+]=[N-]
115.211
115.21
Trimethylsilyl azide
Safety and Handling

Safety and Handling

GHS H Statement
H225-H300-H310-H330
Highly flammable liquid and vapor.
Fatal if swallowed.
Fatal in contact with skin.
Fatal if inhaled.

GHS P Statement
P210-P301+P310-P303+P361+P353-P304+P340-P320-P330-P361-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Specific treatment is urgent (see label).
Rinse mouth.
Remove/Take off immediately all contaminated clothing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Danger

DOTInformation : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, TOXIC, N.O.S.

TSCA : TSCA

Recommended Storage : 2° to 8°C