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Trimethylsilyl azide, 94%, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals L0017306

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Catalog No. AAL0017306



Description

Description

Trimethylsilyl azide is used as an azidonation reagent for amines, amides, aldehydes and ketones. It is involved in the preparation of alfa- and beta-siloxy azides from carbonyl compounds and epoxides. It is also used in the preparation of heterocyclic compounds and also acts as an effective substitute for hydrazoic acid. Further, it is used in the Oseltamivir total synthesis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Trimethylsilyl azide is used as an azidonation reagent for amines, amides, aldehydes and ketones. It is involved in the preparation of alfa- and beta-siloxy azides from carbonyl compounds and epoxides. It is also used in the preparation of heterocyclic compounds and also acts as an effective substitute for hydrazoic acid. Further, it is used in the Oseltamivir total synthesis.

Solubility
Miscible with toluene, dichloromethane, diethyl ether and most organic solvents.

Notes
Moisture sensitive. Store in a cool place. Incompatible with strong oxidizing agents and strong acids.
Specifications

Specifications

Trimethylsilyl azide
-95°C
95°C to 99°C
C3H9N3Si
MFCD00001986
UN1992
Moisture sensitive
Miscible with toluene,dichloromethane,diethyl ether and most organic solvents.
C[Si](C)(C)N=[N+]=[N-]
115.21
115.21
4648-54-8
0.872
6°C (42°F)
1.414
5 g
1903730
trimethylsilyl azide, silane, azidotrimethyl, trimethylsilylazide, azido trimethyl silane, ccris 8048, tms azide, tms-azide, trimethyl silylazide, trimethylsilyl-azide, azido trimethylsilane
SEDZOYHHAIAQIW-UHFFFAOYSA-N
azidotrimethylsilane
78378
94%

Chemical Identifiers

4648-54-8
115.21
SEDZOYHHAIAQIW-UHFFFAOYSA-N
78378
C3H9N3Si
MFCD00001986
trimethylsilyl azide, silane, azidotrimethyl, trimethylsilylazide, azido trimethyl silane, ccris 8048, tms azide, tms-azide, trimethyl silylazide, trimethylsilyl-azide, azido trimethylsilane
C[Si](C)(C)N=[N+]=[N-]
Safety and Handling

Safety and Handling

GHS H Statement
H225-H300-H310-H330
Highly flammable liquid and vapor.
Fatal if swallowed.
Fatal in contact with skin.
Fatal if inhaled.

P210-P233-P235-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P310-P303+P361+P353-P304+P340-P311-P312-P330-P363-P370+P378q-P501c

H225-H301+H311+H331

DOTInformation : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, TOXIC, N.O.S.

EINECSNumber : 225-078-5

TSCA : Yes

Recommended Storage : Keep cold

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