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Alfa Aesar™ Triisopropylsilyl trifluoromethanesulfonate, 97%

$173.50 - $631.50

Chemical Identifiers

Chemical Name or Material Triisopropylsilyl trifluoromethanesulfonate
CAS 80522-42-5
Molecular Formula CF3SO3Si[CH(CH3)2]3
Formula Weight 306.42g/mol
MDL Number MFCD00009913
UN Number UN3265
Beilstein 3591541
Synonym TIPS-OTf; Trifluoromethanesulfonic acid triisopropylsilyl ester
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Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAB2112714

 
alfa aesar™
B21127-14
25g Each for $173.50

AAB2112722

 
alfa aesar™
B21127-22
100g Each for $631.50

AAB2112706

 
alfa aesar™
B21127-06
5g CALL N/A N/A
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Description & Specifications

Specifications

Boiling Point 45° to 46°C (0.03mmHg)
Flash Point 100°C (212°F)
Quantity 25g
Chemical Name or Material Triisopropylsilyl trifluoromethanesulfonate
CAS 80522-42-5
Assay 97%
Molecular Formula CF3SO3Si[CH(CH3)2]3
Formula Weight 306.42g/mol
MDL Number MFCD00009913
UN Number UN3265
Beilstein 3591541
Synonym TIPS-OTf; Trifluoromethanesulfonic acid triisopropylsilyl ester
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.
Health Hazard 3 GHS P Statement
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
DOT Information Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

Applications
Triisopropylsilyl trifluoromethanesulfonate is used as a reagent for the introduction of triisopropylsilyl(TIPS) group in organic synthesis. It is involved in the synthesis of 2-substituted benzothiopyran-4-ones and silyloxy acetylenes. As a protecting group in organic synthesis, it is utilized especially for the protection of primary amines. Furthermore, it plays an important role in Takahashi Taxol total synthesis or for chemical glycosylation reactions.

Solubility
Miscible with chloroform and ethyl acetate.

Notes
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases and strong oxidizing agents. Hydrolyzes in water.

Safety and Handling

Danger

GHS P Statement
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.