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Triethyl phosphonoacetate, 98+%, Thermo Scientific Chemicals
Supplier: Thermo Scientific Chemicals A1412022
Description
Triethyl phosphonoacetate serves as a reactant used in Horner-Wadsworth-Emmons reactions, Tsuji-Trost type reactions, Intramolecular Heck-type cyclization and isomerizations and Intramolecular aryne-ene reactions. In Horner-Wadsworth-Emmons reaction, it is utilized as a reagent to prepare chiral 2-methylcyclopropanecarboxylic acid from (S)-propylene oxide.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsTriethyl phosphonoacetate serves as a reactant used in Horner-Wadsworth-Emmons reactions, Tsuji-Trost type reactions, Intramolecular Heck-type cyclization and isomerizations and Intramolecular aryne-ene reactions. In Horner-Wadsworth-Emmons reaction, it is utilized as a reagent to prepare chiral 2-methylcyclopropanecarboxylic acid from (S)-propylene oxide.
Solubility
Slightly miscible with water.
Notes
Incompatible with strong oxidizing agents.
Specifications
| Triethyl phosphonoacetate | |
| -24°C | |
| 260°C to 262°C | |
| C8H17O5P | |
| MFCD00009177 | |
| 1343714 | |
| Slightly miscible with water. | |
| CCOC(=O)CP(=O)(OCC)OCC | |
| 224.193 | |
| 224.19 |
| 867-13-0 | |
| 1.125 | |
| 165°C (329°F) | |
| 1.431 | |
| 100 g | |
| triethyl phosphonoacetate, ethyl 2-diethoxyphosphoryl acetate, ethyl diethoxyphosphoryl acetate, ethyl diethylphosphono acetate, triethyl phosphonoethanoate, diethyl carboethoxymethylphosphonate, diethyl ethoxycarbonylmethanephosphonate, diethylphosphonoacetic acid ethyl ester, diethyl carbethoxymethylphosphonate | |
| GGUBFICZYGKNTD-UHFFFAOYSA-N | |
| ethyl 2-diethoxyphosphorylacetate | |
| 13345 | |
| ≥98% |
Chemical Identifiers
| 867-13-0 | |
| 224.193 | |
| GGUBFICZYGKNTD-UHFFFAOYSA-N | |
| 13345 | |
| CCOC(=O)CP(=O)(OCC)OCC |
| C8H17O5P | |
| MFCD00009177 | |
| triethyl phosphonoacetate, ethyl 2-diethoxyphosphoryl acetate, ethyl diethoxyphosphoryl acetate, ethyl diethylphosphono acetate, triethyl phosphonoethanoate, diethyl carboethoxymethylphosphonate, diethyl ethoxycarbonylmethanephosphonate, diethylphosphonoacetic acid ethyl ester, diethyl carbethoxymethylphosphonate | |
| ethyl 2-diethoxyphosphorylacetate |
Safety and Handling
GHS H Statement
H315-H319
Causes skin irritation.
Causes serious eye irritation.
P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P310-P312-P332+P313-P362-P501c
H315-H318-H335
EINECSNumber : 212-757-6
RTECSNumber : AG9800000
TSCA : Yes
Recommended Storage : Ambient temperatures
RUO – Research Use Only