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Triethyl 2-phosphonopropionate, 98%, Thermo Scientific Chemicals
Supplier: Thermo Scientific Chemicals B2326118
Description
Triethyl 2-phosphonopropionate is used as a reactant in intramolecular conjugate addition for the synthesis of floresolide B, enantioselective synthesis of spiroindane di-methyl acetic acid and in stereo selective intramolecular Diels-Alder reactions. It plays an important role in Horner-Wadsworth-Emmons reactions and chemoenzymatic one-pot synthesis of gamma-butyrolactones. It is also used in the preparation of 3-[2]furyl-2-methyl-acrylic acid ethyl ester by reacting with furfural.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsTriethyl 2-phosphonopropionate is used as a reactant in intramolecular conjugate addition for the synthesis of floresolide B, enantioselective synthesis of spiroindane di-methyl acetic acid and in stereo selective intramolecular Diels-Alder reactions. It plays an important role in Horner-Wadsworth-Emmons reactions and chemoenzymatic one-pot synthesis of gamma-butyrolactones. It is also used in the preparation of 3-[2]furyl-2-methyl-acrylic acid ethyl ester by reacting with furfural.
Solubility
Miscible with chloroform and methanol.
Notes
Incompatible with strong bases.
Specifications
Triethyl 2-phosphonopropionate | |
1.111 | |
88°C (190°F) | |
C9H19O5P | |
MFCD00009159 | |
1786994 | |
Miscible with chloroform and methanol. | |
CCOC(=O)C(C)P(=O)(OCC)OCC | |
238.22 | |
238.22 |
3699-66-9 | |
143°C to 144°C (12 mmHg) | |
Odorless | |
1.432 | |
50 g | |
triethyl 2-phosphonopropionate, ethyl 2-diethoxyphosphoryl propanoate, ethyl-2-diethylphosphono propanoate, diethyl 1-carbethoxy ethylphosphonate, propanoic acid, 2-diethoxyphosphinyl-, ethyl ester, diethyl ethoxycarbonylethyl-phosphonate, diethyl 1-ethoxycarbonyl ethanephosphonate, 2-diethoxyphosphinyl propanoic acid ethyl ester, diethyl 1-ethoxycarbonyl ethanephosphonate∼2-phosphonopropionic acid triethyl ester, triethyl2-phosphonopropionate | |
BVSRWCMAJISCTD-UHFFFAOYSA-N | |
ethyl 2-diethoxyphosphorylpropanoate | |
107155 | |
98% |
Chemical Identifiers
3699-66-9 | |
238.22 | |
BVSRWCMAJISCTD-UHFFFAOYSA-N | |
107155 | |
CCOC(=O)C(C)P(=O)(OCC)OCC |
C9H19O5P | |
MFCD00009159 | |
triethyl 2-phosphonopropionate, ethyl 2-diethoxyphosphoryl propanoate, ethyl-2-diethylphosphono propanoate, diethyl 1-carbethoxy ethylphosphonate, propanoic acid, 2-diethoxyphosphinyl-, ethyl ester, diethyl ethoxycarbonylethyl-phosphonate, diethyl 1-ethoxycarbonyl ethanephosphonate, 2-diethoxyphosphinyl propanoic acid ethyl ester, diethyl 1-ethoxycarbonyl ethanephosphonate∼2-phosphonopropionic acid triethyl ester, triethyl2-phosphonopropionate | |
ethyl 2-diethoxyphosphorylpropanoate |
Safety and Handling
GHS H Statement
H227
Combustible liquid.
P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c
H227-H315-H319-H335
EINECSNumber : 223-033-4
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only