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Triethyl 2-phosphonopropionate, 98%, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals B2326118

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Catalog No. AAB2326118



Description

Description

Triethyl 2-phosphonopropionate is used as a reactant in intramolecular conjugate addition for the synthesis of floresolide B, enantioselective synthesis of spiroindane di-methyl acetic acid and in stereo selective intramolecular Diels-Alder reactions. It plays an important role in Horner-Wadsworth-Emmons reactions and chemoenzymatic one-pot synthesis of gamma-butyrolactones. It is also used in the preparation of 3-[2]furyl-2-methyl-acrylic acid ethyl ester by reacting with furfural.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Triethyl 2-phosphonopropionate is used as a reactant in intramolecular conjugate addition for the synthesis of floresolide B, enantioselective synthesis of spiroindane di-methyl acetic acid and in stereo selective intramolecular Diels-Alder reactions. It plays an important role in Horner-Wadsworth-Emmons reactions and chemoenzymatic one-pot synthesis of gamma-butyrolactones. It is also used in the preparation of 3-[2]furyl-2-methyl-acrylic acid ethyl ester by reacting with furfural.

Solubility
Miscible with chloroform and methanol.

Notes
Incompatible with strong bases.
Specifications

Specifications

Triethyl 2-phosphonopropionate
1.111
88°C (190°F)
C9H19O5P
MFCD00009159
1786994
Miscible with chloroform and methanol.
CCOC(=O)C(C)P(=O)(OCC)OCC
238.22
238.22
3699-66-9
143°C to 144°C (12 mmHg)
Odorless
1.432
50 g
triethyl 2-phosphonopropionate, ethyl 2-diethoxyphosphoryl propanoate, ethyl-2-diethylphosphono propanoate, diethyl 1-carbethoxy ethylphosphonate, propanoic acid, 2-diethoxyphosphinyl-, ethyl ester, diethyl ethoxycarbonylethyl-phosphonate, diethyl 1-ethoxycarbonyl ethanephosphonate, 2-diethoxyphosphinyl propanoic acid ethyl ester, diethyl 1-ethoxycarbonyl ethanephosphonate∼2-phosphonopropionic acid triethyl ester, triethyl2-phosphonopropionate
BVSRWCMAJISCTD-UHFFFAOYSA-N
ethyl 2-diethoxyphosphorylpropanoate
107155
98%

Chemical Identifiers

3699-66-9
238.22
BVSRWCMAJISCTD-UHFFFAOYSA-N
107155
CCOC(=O)C(C)P(=O)(OCC)OCC
C9H19O5P
MFCD00009159
triethyl 2-phosphonopropionate, ethyl 2-diethoxyphosphoryl propanoate, ethyl-2-diethylphosphono propanoate, diethyl 1-carbethoxy ethylphosphonate, propanoic acid, 2-diethoxyphosphinyl-, ethyl ester, diethyl ethoxycarbonylethyl-phosphonate, diethyl 1-ethoxycarbonyl ethanephosphonate, 2-diethoxyphosphinyl propanoic acid ethyl ester, diethyl 1-ethoxycarbonyl ethanephosphonate∼2-phosphonopropionic acid triethyl ester, triethyl2-phosphonopropionate
ethyl 2-diethoxyphosphorylpropanoate
Safety and Handling

Safety and Handling

GHS H Statement
H227
Combustible liquid.

P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c

H227-H315-H319-H335

EINECSNumber : 223-033-4

TSCA : No

Recommended Storage : Ambient temperatures

SDS
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