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Tetra-n-butylphosphonium bromide, 99%

CAS: 3115-68-2 | C16H36BrP | 339.342 g/mol

Supplier:  Thermo Scientific Chemicals A1086836

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Catalog No. AAA1086836


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Description

Description

Tetra-n-butylphosphonium bromide is used as a phase-transfer catalyst at high temperatures, at which nitrogen analogues tend to undergo elimination e.g. as catalyst for the dealkoxycarbonylation of malonates and β-keto esters by heating in stearic acid. used as an ionic liquid solvent in the regioselective O-alkylation of C/O ambident nucleophiles. It is a synthetic reagent used in proteomics research.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Tetra-n-butylphosphonium bromide is used as a phase-transfer catalyst at high temperatures, at which nitrogen analogues tend to undergo elimination e.g. as catalyst for the dealkoxycarbonylation of malonates and ß-keto esters by heating in stearic acid. used as an ionic liquid solvent in the regioselective O-alkylation of C/O ambident nucleophiles. It is a synthetic reagent used in proteomics research.

Solubility
Soluble in water (70 g/100 ml)

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. It is hygroscopic in nature.
Specifications

Specifications

Tetra-n-butylphosphonium bromide
99°C to 103°C
C16H36BrP
MFCD00011853
UN3464
Hygroscopic
Soluble in water (70g/100 ml)
CCCC[P+](CCCC)(CCCC)CCCC.[Br-]
339.342
339.35
3115-68-2
290°C (554°F)
[CH3(CH2)3]4PBr
500 g
4160474
tetrabutylphosphonium bromide, tetra-n-butylphosphonium bromide, phosphonium, tetrabutyl-, bromide, px 4b, tetra butyl phosphonium bromide, tetrabutylphosphoniumbromide, tetrabutylphosphanium bromide, tetrabutyl phosphonium bromide, phosphonium, tetrabutyl-, bromide 1:1, acmc-1clh3
RKHXQBLJXBGEKF-UHFFFAOYSA-M
tetrabutylphosphanium;bromide
76564
99%

Chemical Identifiers

3115-68-2
339.342
RKHXQBLJXBGEKF-UHFFFAOYSA-M
76564
CCCC[P+](CCCC)(CCCC)CCCC.[Br-]
C16H36BrP
MFCD00011853
tetrabutylphosphonium bromide, tetra-n-butylphosphonium bromide, phosphonium, tetrabutyl-, bromide, px 4b, tetra butyl phosphonium bromide, tetrabutylphosphoniumbromide, tetrabutylphosphanium bromide, tetrabutyl phosphonium bromide, phosphonium, tetrabutyl-, bromide 1:1, acmc-1clh3
tetrabutylphosphanium;bromide
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Safety and Handling

Safety and Handling

GHS H Statement
H310-H318-H302-H332-H315-H335
Fatal in contact with skin.
Causes serious eye damage.
Harmful if swallowed.
Harmful if inhaled.
Causes skin irritation.
May cause respiratory irritation.

P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P361-P363-P501c

H302+H332-H311-H315-H319-H335

DOTInformation : Transport Hazard Class: 6.1; Packing Group: II; Proper Shipping Name: ORGANOPHOSPHORUS COMPOUND, TOXIC, SOLID, N.O.S.

EINECSNumber : 221-487-8

RTECSNumber : TA2417000

TSCA : Yes

Recommended Storage : Ambient temperatures; Store under Argon

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RUO – Research Use Only