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Tetra-n-butylammonium bromide, 98+%, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals A102490E

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Catalog No. AAA102490E



Description

Description

Phase transfer catalyst Tetra-n-butylammonium bromide is used as a phase transfer catalyst for the preparation of lactones by cyclization of potassium salt of μ-bromocarboxylic acids and beta-lactones from beta-bromoacid by cyclization. It is also involved in the Curtius rearrangement, N-alkylation of aromatic carboxamides. It plays an important role as an ionic liquid in the regioselective O-alkylation reactions. It is also used in the preparation of polymer solar cells and single component green-light emitting electrochemical cells.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Phase transfer catalyst Tetra-n-butylammonium bromide is used as a phase transfer catalyst for the preparation of lactones by cyclization of potassium salt of µ-bromocarboxylic acids and beta-lactones from beta-bromoacid by cyclization. It is also involved in the Curtius rearrangement, N-alkylation of aromatic carboxamides. It plays an important role as an ionic liquid in the regioselective O-alkylation reactions. It is also used in the preparation of polymer solar cells and single component green-light emitting electrochemical cells.

Solubility
Soluble in water and ethanol.

Notes
Hygroscopic. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.
Specifications

Specifications

Tetra-n-butylammonium bromide
101°C to 105°C
Amine-like
[CH3(CH2)3]4NBr
2500 g
Hygroscopic
Soluble in water and ethanol.
CCCC[N+](CCCC)(CCCC)CCCC.[Br-]
322.375
CHEBI:51993
≥98%
1643-19-2
1.15
C16H36BrN
MFCD00011633
3570983
tetrabutylammonium bromide, tetra-n-butylammonium bromide, tbab, tetrabutylazanium bromide, tetrabutyl ammonium bromide, tetrabutyl-ammonium bromide, aliquat 100, tbabr, ipc-tba-br, unii-vjz168i98r
JRMUNVKIHCOMHV-UHFFFAOYSA-M
tetrabutylazanium;bromide
74236
322.38

Chemical Identifiers

1643-19-2
322.375
JRMUNVKIHCOMHV-UHFFFAOYSA-M
74236
tetrabutylazanium;bromide
C16H36BrN
MFCD00011633
tetrabutylammonium bromide, tetra-n-butylammonium bromide, tbab, tetrabutylazanium bromide, tetrabutyl ammonium bromide, tetrabutyl-ammonium bromide, aliquat 100, tbabr, ipc-tba-br, unii-vjz168i98r
CHEBI:51993
CCCC[N+](CCCC)(CCCC)CCCC.[Br-]
Safety and Handling

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

EINECSNumber : 216-699-2

TSCA : Yes

Recommended Storage : Ambient temperatures; Store under Argon

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