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tert-Butyl hydroperoxide, 70% aq. soln.

Manufacturer:  Alfa Aesar A13926AP

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Catalog No. AAA13926AP


 

Description

Description

Applications
tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis.

Solubility
Miscible with water and diethyl ether.

Notes
Light sensitive. Store in cool place. Incompatible with powdered metals, strong oxidizing agents, reducing agents, acids, alkalis and heavy metals.
Specifications

Specifications

tert-Butyl Hydroperoxide
0.937
70% Aqueous Solution
(CH3)3COOH
UN3109
14,1570
CC(C)(C)OO
90.122
CHEBI:64090
75-91-2
500mL
C4H10O2
MFCD00002130
1098280
CIHOLLKRGTVIJN-UHFFFAOYSA-N
2-hydroperoxy-2-methylpropane
6410
90.12

Chemical Identifiers

75-91-2
90.122
CIHOLLKRGTVIJN-UHFFFAOYSA-N
CHEBI:64090
C4H10O2
MFCD00002130
6410
Safety and Handling

Safety and Handling

GHS H Statement
H300-H310-H330-H314-H226-H242
Fatal if swallowed.
Fatal in contact with skin.
Fatal if inhaled.
Causes severe skin burns and eye damage.
Flammable liquid and vapour.
Heating may cause a fire.

GHS P Statement
P210-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P361-P405-P410-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

Danger

DOTInformation : Transport Hazard Class: 5.2; Packing Group: II; Proper Shipping Name: ORGANIC PEROXIDE TYPE F, LIQUID

RTECSNumber : EQ4900000

TSCA : TSCA

Recommended Storage : 2° to 8°C

SDS Documents