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Alfa Aesar™ tert-Butyl hydroperoxide, 70% aq. soln.

$32.64 - $71.43

Chemical Identifiers

CAS 75-91-2
Molecular Formula C4H10O2
Linear Formula (CH3)3COOH
Formula Weight 90.12
MDL Number MFCD00002130
UN Number UN3109
Beilstein 1098280
Merck Index 14,1570
Synonym TBHP
Chemical Name or Material tert-Butyl hydroperoxide
View More Specs


Products ${productFamilyLength}
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AAA13926AE SDS Alfa Aesar™
A13926AE
100mL Each for $32.64
AAA139260F SDS Alfa Aesar™
A139260F
2500mL N/A N/A  
Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
AAA13926AP SDS Alfa Aesar
A13926AP
500mL Each for $71.43
Specifications

Description

Applications
tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis.

Solubility
Miscible with water and diethyl ether.

Notes
Light sensitive. Store in cool place. Incompatible with powdered metals, strong oxidizing agents, reducing agents, acids, alkalis and heavy metals.
Description & Specifications

Chemical Identifiers

75-91-2
(CH3)3COOH
MFCD00002130
1098280
TBHP
C4H10O2
90.12
UN3109
14,1570
tert-Butyl hydroperoxide

Specifications

75-91-2
C4H10O2
90.12
UN3109
14,1570
96°C (dec.)
43°C (109°F)
100mL
70% Aqueous Solution
(CH3)3COOH
MFCD00002130
1098280
TBHP
−3°C
70% aq. soln.
tert-Butyl hydroperoxide

Safety and Handling

GHS H Statement
H300-H310-H330-H314-H226-H242
Fatal if swallowed.
Fatal in contact with skin.
Fatal if inhaled.
Causes severe skin burns and eye damage.
Flammable liquid and vapour.
Heating may cause a fire.

GHS P Statement
P210-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P361-P405-P410-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Specific treatment is urgent (see label).
Rinse mouth.
Remove/Take off immediately all contaminated clothing.
Store locked up.
Protect from sunlight.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Danger

DOTInformation : Transport Hazard Class: 5.2; Packing Group: II; Proper Shipping Name: ORGANIC PEROXIDE TYPE F, LIQUID

RTECSNumber : EQ4900000

TSCA : TSCA

Recommended Storage : 2° to 8°C