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Alfa Aesar™ Sodium bis(trimethylsilyl)amide, 2M soln. in THF

Manufacturer:  Alfa Aesar™ L13352AE

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Catalog No. AAL13352AE



Description

Description

Applications
Sodium bis(trimethylsilyl)amide is a strong base used in organic synthesis for deprotonation reactions and base catalyzed reaction. It is also used to enhance the polymerization of pheneylacetylene in conjunction with rhodium(I) catalysis. It is involved in the generation of enolates, Wittig reagents and carbenes.

Solubility
Miscible with benzene and toluene.

Notes
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents, strong oxidizing agents and oxygen. Dry residue is explosive.
Specifications

Specifications

Sodium bis(trimethylsilyl)amide
C6H18NNaSi2
UN2924
sodium bis trimethylsilyl amide, n-sodiohexamethyldisilazane, sodium hexamethyldisilazide, nahmds, sodiobis trimethylsilyl amine, sodium bis trimethylsilyl azanide, n-sodium hexamethyldisilazane, sodium-bis trimethylsilyl amide, hexamethyldisilazane sodium salt, sodium bis trimethylsilyl amide
C[Si](C)(C)[N-][Si](C)(C)C.[Na+]
183.377
183.38
100mL
1070-89-9
MFCD00009835
3629917
WRIKHQLVHPKCJU-UHFFFAOYSA-N
sodium;bis(trimethylsilyl)azanide
2724254
2M soln. in THF
−17°C (1°F)

Chemical Identifiers

1070-89-9
183.377
WRIKHQLVHPKCJU-UHFFFAOYSA-N
2724254
C[Si](C)(C)[N-][Si](C)(C)C.[Na+]
C6H18NNaSi2
MFCD00009835
sodium bis trimethylsilyl amide, n-sodiohexamethyldisilazane, sodium hexamethyldisilazide, nahmds, sodiobis trimethylsilyl amine, sodium bis trimethylsilyl azanide, n-sodium hexamethyldisilazane, sodium-bis trimethylsilyl amide, hexamethyldisilazane sodium salt, sodium bis trimethylsilyl amide
sodium;bis(trimethylsilyl)azanide
Safety and Handling

Safety and Handling

GHS H Statement
H225-H314-H351-H335
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
Suspected of causing cancer.
May cause respiratory irritation.

GHS P Statement
P210-P260-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Danger

DOTInformation : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.

TSCA : TSCA

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