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Alfa Aesar™ Sodium bis(trimethylsilyl)amide, 1M soln. in THF

$65.73 - $65.73

Chemical Identifiers

CAS 1070-89-9
Molecular Formula C6H18NNaSi2
Formula Weight 183.38
MDL Number MFCD00009835
UN Number UN2924
Beilstein 3629917
Synonym NaHMDS; N-Sodiohexamethyldisilazane
Chemical Name or Material Sodium bis(trimethylsilyl)amide
View More Specs


Products ${productFamilyLength}
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AAL08779AP SDS Alfa Aesar™
L08779AP
500mL N/A N/A  
Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
AAL08779AE SDS Alfa Aesar™
L08779AE*
100mL Each for $65.73
Specifications

Description

Applications
Sodium bis(trimethylsilyl)amide is useful for the generation of carbenes, the amination of sulfonamides, and for the preparation of lanthanide complexes. It is significantly accelerated the polymerization of pheneylacetylene in conjunction with rhodium (I) catalysis. It is used to deprotonate ketones and esters to generate enolate derivatives, phosphonium salts, generating Wittig reagents.

Solubility
Soluble in benzene, toluene and ether. Reacts with water.

Notes
Moisture Sensitive. Incompatible materials are Oxidizing agents, Oxygen. Store away from water and oxidizing agents.
Description & Specifications

Chemical Identifiers

1070-89-9
183.38
UN2924
NaHMDS; N-Sodiohexamethyldisilazane
C6H18NNaSi2
MFCD00009835
3629917
Sodium bis(trimethylsilyl)amide

Specifications

1070-89-9
183.38
UN2924
NaHMDS; N-Sodiohexamethyldisilazane
500mL
Sodium bis(trimethylsilyl)amide
C6H18NNaSi2
MFCD00009835
3629917
1M soln. in THF
−17°C (1°F)

Safety and Handling

GHS H Statement
H225-H314-H351-H335
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
Suspected of causing cancer.
May cause respiratory irritation.

GHS P Statement
P210-P260-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Danger

DOTInformation : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.

TSCA : TSCA