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Alfa Aesar™ Sodium bis(trimethylsilyl)amide, 1M soln. in THF

Manufacturer:  Alfa Aesar™ L08779AP

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Catalog No. AAL08779AP

 

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Specifications

Description

Sodium bis(trimethylsilyl)amide; Alfa Aesar; 500mL; FW: 183.38; C6H18NNaSi2; CAS: 1070-89-9

Applications
Sodium bis(trimethylsilyl)amide is useful for the generation of carbenes, the amination of sulfonamides, and for the preparation of lanthanide complexes. It is significantly accelerated the polymerization of pheneylacetylene in conjunction with rhodium (I) catalysis. It is used to deprotonate ketones and esters to generate enolate derivatives, phosphonium salts, generating Wittig reagents.

Solubility
Soluble in benzene, toluene and ether. Reacts with water.

Notes
Moisture Sensitive. Incompatible materials are Oxidizing agents, Oxygen. Store away from water and oxidizing agents.
Description & Specifications

Specifications

Sodium bis(trimethylsilyl)amide
C6H18NNaSi2
MFCD00009835
3629917
1M soln. in THF
−17°C (1°F)
1070-89-9
183.38
UN2924
NaHMDS; N-Sodiohexamethyldisilazane
500mL

Chemical Identifiers

1070-89-9
183.38
UN2924
NaHMDS; N-Sodiohexamethyldisilazane
C6H18NNaSi2
MFCD00009835
3629917
Sodium bis(trimethylsilyl)amide

Safety and Handling

SDS & Safety Documents

GHS H Statement
H225-H314-H351-H335
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
Suspected of causing cancer.
May cause respiratory irritation.

GHS P Statement
P210-P260-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Danger

DOTInformation : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.

TSCA : TSCA