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Alfa Aesar™ (S)-(-)-1-(4-Chlorophenyl)ethylamine, ChiPros™ 97%, ee 98%

Chemical Identifiers

Chemical Name or Material (S)-(-)-1-(4-Chlorophenyl)ethylamine
CAS 4187-56-8
Molecular Formula C8H10ClN
Formula Weight 155.63
MDL Number MFCD00671640
UN Number UN2922
Beilstein 2412316
Synonym (S)-4-Chloro-alpha-methylbenzylamine; ClophaS
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAL1905206

 
alfa aesar™
L1905206
5g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.

AAL1905214

 
alfa aesar™
L1905214
25g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Description & Specifications

Specifications

Formula Weight 155.63
Chemical Name or Material (S)-(-)-1-(4-Chlorophenyl)ethylamine
Assay 97%
Molecular Formula C8H10ClN
MDL Number MFCD00671640
CAS 4187-56-8
Beilstein 2412316
Synonym (S)-4-Chloro-alpha-methylbenzylamine; ClophaS
Health Hazard 1 Danger
Quantity 5g
DOT Information Transport Hazard Class: 8; Packing Group: III; Proper Shipping Name: CORROSIVE LIQUIDS, TOXIC, N.O.S.
Assay Percent Notes ee 98%
UN Number UN2922
Health Hazard 2 GHS H Statement
H301-H330-H314-H318
Toxic if swallowed.
Fatal if inhaled.
Causes severe skin burns and eye damage.
Causes serious eye damage.
Health Hazard 3 GHS P Statement
P260-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Specific treatment is urgent (see label).
Rinse mouth.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Boiling Point 232°C
Flash Point 115°C (239°F)
Odor Pungent
Optical Rotation −31° (Neat)

Applications
It is used as a substrate in palladium catalysts on alkaline-earth supports for racemization and dynamic kinetic resolution of benzylic amines.

Solubility
Soluble in water at 25°C 11 g/L.

Notes
Air sensitive. Store away from acids, air, acid chlorides, acid anhydrides and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

Safety and Handling

Danger

GHS P Statement
P260-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Specific treatment is urgent (see label).
Rinse mouth.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H301-H330-H314-H318
Toxic if swallowed.
Fatal if inhaled.
Causes severe skin burns and eye damage.
Causes serious eye damage.